(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

Base Information

Chemical Name:(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene
CAS No.:910792-92-6
Molecular Formula:C₂₉H₅₆O₂Si₃
Molecular Weight:521.019
Hs Code.:

Synonyms:(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

Suppliers and Price of (3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

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Technology Process of (3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

There total 1 articles about (3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6485-79-6
chlorotriisopropylsilane

: 87727-28-4
(S)-2-tert-butyl-dimethyl-silanyloxy propanal

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

: (3R,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

: 910792-92-6
(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

Guidance literature:: With potassium tert-butylate; 1,3-bis(mesityl)imidazolium chloride; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In tetrahydrofuran; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1021/ol061579u

Reference yield: 98.0%

: 910792-92-6
(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

: 67470-74-0
(2S,3R,E)-5-phenylpent-4-ene-2,3-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1021/ol061579u

Reference yield:

: 910792-92-6
(3S,4S,Z)-4-(tert-butyldimethylsiloxy)-1-phenyl-3-(triisopropylsiloxy)-2-(trimethylsilyl)pent-1-ene

: (3R,4S,E)-3,4-dibenzyloxy-1-phenylpent-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 20 °C

2: 56 mg / NaH; Bu₄NI / tetrahydrofuran / 4 h / 20 °C

With tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran;
DOI:10.1021/ol061579u