4-hydroxy-3-methyl-2-butenyl phenyl sulfide

Base Information

• Chemical Name: 4-hydroxy-3-methyl-2-butenyl phenyl sulfide
• CAS No.: 23451-77-6
• Molecular Formula: C₁₁H₁₄OS
• Molecular Weight: 194.298
• Mol file: 23451-77-6.mol

Synonyms:4-hydroxy-3-methyl-2-butenyl phenyl sulfide

Chemical Property of 4-hydroxy-3-methyl-2-butenyl phenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-hydroxy-3-methyl-2-butenyl phenyl sulfide

There total 2 articles about 4-hydroxy-3-methyl-2-butenyl phenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

thiophenol; bismuth (III)-benzenethiolate (60458-23-3) + isoprene epoxide (1838-94-4) → 4-hydroxy-3-methyl-2-butenyl phenyl sulfide (23451-77-6)

Guidance literature:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In water; N,N-dimethyl-formamide; at 20 ℃; for 12h;

DOI:10.1081/SCC-100104838

Reference yield:

→ 4-hydroxy-3-methyl-2-butenyl phenyl sulfide (23451-77-6)

Guidance literature:

Aus Isoprenoxid-(1,2), Phenylmercaptan;

Reference yield:

4-hydroxy-3-methyl-2-butenyl phenyl sulfide (23451-77-6) → (E)-4-Benzenesulfinyl-2-methyl-but-2-en-1-ol + (Z)-4-Benzenesulfinyl-2-methyl-but-2-en-1-ol

Guidance literature:

With dihydrogen peroxide; 5-ethyl-1,3-dimethyl-1,5-dihydroflavine; In methanol; water; at 20 ℃; for 2h; Title compound not separated from byproducts;

DOI:10.1021/jo034273z

upstream raw materials:

thiophenol; bismuth (III)-benzenethiolate

isoprene epoxide

Downstream raw materials:

(E)-4-chloro-3-methyl-2-butenyl phenyl sulfide