(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

Base Information

Chemical Name:(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester
CAS No.:106693-63-4
Molecular Formula:C₂₃H₂₉N₃O₈S
Molecular Weight:507.565
Hs Code.:

Synonyms:(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

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Chemical Property of (S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

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Technology Process of (S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

There total 5 articles about (S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 40630-84-0
allyl bromoacetate

: 106693-63-4
(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) THF, -15 deg C, 80 min, 2.)THF, addition 30 min, below 0 deg C, then -5 deg C, 15 min

2: 100 percent / Br₂, Et₃N / CHCl₃ / addition -20 deg C, 1 h, then 30 min -20 deg C and r.t.

3: 1,2-dichloro-ethane / 1 h / Heating

With bromine; sodium hydride; triethylamine; In chloroform; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(01)85943-3

Reference yield:

: 106693-59-8
allyl 3-(phenylsulfonyl)-4-oxopentanoate

: 106693-63-4
(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / Br₂, Et₃N / CHCl₃ / addition -20 deg C, 1 h, then 30 min -20 deg C and r.t.

2: 1,2-dichloro-ethane / 1 h / Heating

With bromine; triethylamine; In chloroform; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(01)85943-3

Reference yield:

: 5000-44-2
1-phenylsulfonyl-2-propanone

: 106693-63-4
(S)-2-Acetyl-2-benzenesulfonyl-6-tert-butoxycarbonylamino-7-oxo-tetrahydro-pyrazolo[1,2-a]pyrazole-1-carboxylic acid allyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) THF, -15 deg C, 80 min, 2.)THF, addition 30 min, below 0 deg C, then -5 deg C, 15 min

2: 100 percent / Br₂, Et₃N / CHCl₃ / addition -20 deg C, 1 h, then 30 min -20 deg C and r.t.

3: 1,2-dichloro-ethane / 1 h / Heating

With bromine; sodium hydride; triethylamine; In chloroform; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(01)85943-3