9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene

Base Information

• Chemical Name: 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene
• CAS No.: 626236-82-6
• Molecular Formula: C₃₈H₅₄N₂O₂
• Molecular Weight: 570.859

Synonyms:9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene

Chemical Property of 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene

Chemical Property:

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Technology Process of 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene

There total 2 articles about 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

N,N'-dibenzyl-1,6-diaminohexane (30070-99-6) + 6-[4-(6-oxohexyloxy)phenoxy]hexanal (626236-81-5) → 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1(27),24(28),25-triene (626236-82-6)

Guidance literature:

With acetylacetonatodicarbonylrhodium(l); hydrogen; In toluene; at 50 ℃; for 24h; under 30002.4 Torr;

DOI:10.1016/j.tet.2003.08.012

Reference yield:

1,4-bis(pent-4-enyloxy)benzene (482606-31-5) → 9,16-dibenzyl-2,23-dioxa-9,16-diaza-bicyclo[22.2.2]octacosa-1(27),24(28),25-triene (626236-82-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / H₂; [Rh(acac)(CO)2]; XANTPHOS / toluene / 18 h / 120 °C / 60004.8 Torr

2: 53 percent / H₂; [Rh(acac)(CO)2] / toluene / 24 h / 50 °C / 30002.4 Torr

With acetylacetonatodicarbonylrhodium(l); hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; In toluene;

DOI:10.1016/j.tet.2003.08.012

upstream raw materials:

N,N'-dibenzyl-1,6-diaminohexane

6-[4-(6-oxohexyloxy)phenoxy]hexanal

1,4-bis(pent-4-enyloxy)benzene

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