(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

Base Information

Chemical Name:(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester
CAS No.:828246-57-7
Molecular Formula:C₃₂H₄₂O₄Si₂
Molecular Weight:546.854
Hs Code.:

(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

Synonyms:(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

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Chemical Property of (6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

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Technology Process of (6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

There total 3 articles about (6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: (R)-6-[1-(Diphenyl-vinyl-silanyloxymethyl)-vinyl]-3-methyl-2-oxo-cyclohex-3-enecarboxylic acid methyl ester

: 828246-57-7
(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

Guidance literature:: (R)-6-[1-(Diphenyl-vinyl-silanyloxymethyl)-vinyl]-3-methyl-2-oxo-cyclohex-3-enecarboxylic acid methyl ester; With lithium hexamethyldisilazane; In hexane; dichloromethane; at -78 ℃; for 0.5h;

t-butyldimethylsiyl triflate; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
DOI:10.3390/90500287

Reference yield:

: 18419-53-9
vinyldiphenylchlorosilane

: 828246-57-7
(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 80 percent / Et₃N / tetrahydrofuran / 1 h / -20 °C

2.1: LDA / tetrahydrofuran / 2.5 h / -78 - 0 °C

2.2: 82 percent / HMPA / tetrahydrofuran / 0.5 h / -78 °C

3.1: LiN[Si(CH₃)3]2 / CH₂Cl₂; hexane / 0.5 h / -78 °C

3.2: 83 percent / tetrahydrofuran; hexane / 1 h / -78 °C

With triethylamine; lithium hexamethyldisilazane; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.3390/90500287

Reference yield:

: 828246-52-2
(R)-5-[1-(Diphenyl-vinyl-silanyloxymethyl)-vinyl]-2-methyl-cyclohex-2-enone

: 828246-57-7
(6S)-2-[(tert-butyldimethylsilanyl)oxy]-6-[1-(diphenylvinylsilanyloxymethyl)vinyl]-3-methylcyclohexa-1,3-diene-1-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 2.5 h / -78 - 0 °C

1.2: 82 percent / HMPA / tetrahydrofuran / 0.5 h / -78 °C

2.1: LiN[Si(CH₃)3]2 / CH₂Cl₂; hexane / 0.5 h / -78 °C

2.2: 83 percent / tetrahydrofuran; hexane / 1 h / -78 °C

With lithium hexamethyldisilazane; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.3390/90500287