cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)]

Base Information

• Chemical Name: cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)]
• CAS No.: 257888-40-7
• Molecular Formula: C₁₇H₂₀Pt
• Molecular Weight: 419.426
• Mol file: 257888-40-7.mol

Synonyms:cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)]

Chemical Property of cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)]

There total 4 articles about cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

chloro(methyl)(1,5-cyclooctadiene)platinum(II) (50978-00-2) + phenylacetylene (536-74-3) → cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)] (257888-40-7)

Guidance literature:

With potassium tert-butylate; In ethanol; at -5 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/om400293u

Reference yield: 77.0%

chloromethyl(1,5-cyclooctadiene)platinum(II) + phenylacetylene (536-74-3) → cis-[(1,5-cyclooctadiene)Pt(Me)(CCPh)] (257888-40-7)

Guidance literature:

With NaOEt or t-BuOK; In ethanol; byproducts: NaCl, HOEt; (Ar); Schlenk technique; mixt. of alkyne (1.1 equiv.) and NaOEt (or t-BuOK) (1.1 equiv.) in EtOH was added dropwise with stirring to suspn. of Pt complex in EtOH at -30°C; reacted for 2 h; filtered; recrystd. (CH2Cl2/heptane); elem. anal.;

DOI:10.1016/j.jorganchem.2010.04.027

Reference yield: 71.0%

[(1,5-cyclooctadiene)PtMe(OH)] (257888-38-3) + phenylacetylene (536-74-3) → [(1,5-cyclooctadiene)PtMe(C.tplbond.CPh)] (257888-40-7)

Guidance literature:

In tetrahydrofuran; Ar-atmosphere; excess of PhC2H, stirring for 1 h; filtration, evapn., washing (heptane); elem. anal.;

DOI:10.1016/S0022-328X(99)00500-8

upstream raw materials:

[(1,5-cyclooctadiene)PtMe(OH)]

phenylacetylene

chloro(methyl)(1,5-cyclooctadiene)platinum(II)