1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

Base Information

Chemical Name:1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose
CAS No.:405215-55-6
Molecular Formula:C₂₂H₂₇NO₈
Molecular Weight:433.458
Hs Code.:

Synonyms:1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

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Chemical Property of 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

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Technology Process of 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

There total 7 articles about 1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 405215-54-5
(3aR,4R,6aS)-4-[(S)-Hydroxy-((1S,5R)-4-oxo-6,8-dioxa-bicyclo[3.2.1]oct-2-en-3-yl)-methyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester

: 405215-55-6
1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol; dichloromethane; at -10 ℃; for 0.333333h;

Reference yield:

: 37112-31-5
levoglucosenone

: 405215-55-6
1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 38 percent / Et₂AlI / hexane; CH₂Cl₂ / 4 h / -35 °C

2: 93 percent / CeCl₃*7H₂O; NaBH₄ / CH₂Cl₂; methanol / 0.33 h / -10 °C

With sodium tetrahydroborate; cerium(III) chloride; diethylaluminum iodide; In methanol; hexane; dichloromethane;

Reference yield:

: 117859-46-8
1,4-Dideoxy-2,3:5,6-di-O-isopropylidene-1,4-imino-D-allitol

: 405215-55-6
1,6-anhydro-3,4-dideoxy-3-[(1'S)-N-benzyloxycarbonyl-3',4'-O-isopropylidene-2',5'-dideoxy-2',5'-imino-D-ribitol-1'-C-yl]-D-threo-hex-3-enopyranose

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / NaHCO₃ / ethanol; H₂O / 0.67 h / 20 °C

2: 68 percent / AcOH; water / 10 h / 20 °C

3: 94 percent / NaHCO₃; Pb(OAc)4 / CH₂Cl₂ / 0.83 h / -78 °C

4: 38 percent / Et₂AlI / hexane; CH₂Cl₂ / 4 h / -35 °C

5: 93 percent / CeCl₃*7H₂O; NaBH₄ / CH₂Cl₂; methanol / 0.33 h / -10 °C

With lead(IV) acetate; sodium tetrahydroborate; cerium(III) chloride; water; diethylaluminum iodide; sodium hydrogencarbonate; acetic acid; In methanol; ethanol; hexane; dichloromethane; water;