rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine)

Base Information

• Chemical Name: rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine)
• CAS No.: 476613-12-4
• Molecular Formula: C₂₀H₁₆N₃O₃Re
• Molecular Weight: 532.572
• Mol file: 476613-12-4.mol

Synonyms:rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine)

Chemical Property of rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine)

There total 1 articles about rhenium(NCH₃C₆H₅)(CO)3(2,2'-bipyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

(2,2'-bipyridine)tricarbonylrhenium trifluoromethanesulfonate (97170-94-0,142939-90-0) + potassium N-methylanilide → rhenium(NCH3C6H5)(CO)3(2,2'-bipyridine) (476613-12-4)

Guidance literature:

In tetrahydrofuran; soln. of KNCH3C6H5 in THF added to soln. of Re(OOSO3CF3)(CO)3(C5H4N)2 inTHF cooled to -78 °C, mixt. allowed to reach room temp.; volatiles removed (vac.), solid extd. with CH2Cl2, soln. filtered using cannula tipped with filter paper; elem. anal.;

DOI:10.1039/b203261a

Reference yield: 88.0%

rhenium(NCH3C6H5)(CO)3(2,2'-bipyridine) (476613-12-4) + p-Tolylisocyanate (622-58-2,374675-64-6) → rhenium(N-p-C6H4CH3)(CONCH3C6H5)(CO)3(2,2'-bipyridine) (476613-13-5)

Guidance literature:

In tetrahydrofuran; CH3C6H4NCO added to soln. of Re(NCH3C6H4)(CO)3(C5H4N)2 in THF, mixt. stirred for 15 min; solvent removed (vac.), solid redissolved in CH2Cl2, slow diffusion of hexane into this soln. at -20 °C; elem. anal.;

DOI:10.1039/b203261a

upstream raw materials:

(2,2'-bipyridine)tricarbonylrhenium trifluoromethanesulfonate

Downstream raw materials:

rhenium(N-p-C₆H₄CH₃)(CONCH₃C₆H₅)(CO)3(2,2'-bipyridine)