<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Base Information

Chemical Name:<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester
CAS No.:113453-44-4
Molecular Formula:C₄₆H₆₄O₈
Molecular Weight:745.009
Hs Code.:

<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Synonyms:<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

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Chemical Property of <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

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Technology Process of <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

There total 1 articles about <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 113453-43-3
<3(2R,2(2S,3S,6R,6(2R,3R,4R,7S,7(4R)))),4R,5R>-3-<2-<6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-4-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-3-methyl-2-tetrahydropyranyl>-1-oxopropyl>-4-methyl-5-phenyl-2-oxazolidinone

: 100-51-6,185532-71-2
benzyl alcohol

: 113453-44-4
<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Guidance literature:: With n-butyllithium; In tetrahydrofuran; -30 - 0 deg C, 3 h; 0 deg C, 6 h;
DOI:10.1021/ja00216a026

Reference yield: 90.0%

: 113453-44-4
<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

: 113453-45-5
<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Guidance literature:: With sulfuric acid; In tetrahydrofuran; ethanol; at 50 ℃; for 5h;
DOI:10.1021/ja00216a026

Reference yield:

: 113453-44-4
<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

: 113453-46-6
<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3,7-dimethyl-8-oxo-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / 1M aq. H₂SO₄ / tetrahydrofuran; ethanol / 5 h / 50 °C

2: 95 percent / NaIO₄ / acetone; H₂O / 5 h / Ambient temperature

With sodium periodate; sulfuric acid; In tetrahydrofuran; ethanol; water; acetone;
DOI:10.1021/ja00216a026