methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate

Base Information

• Chemical Name: methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate
• CAS No.: 82159-67-9
• Molecular Formula: C₃₃H₃₅NO₁₀
• Molecular Weight: 605.642
• Mol file: 82159-67-9.mol

Synonyms:methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate

Chemical Property of methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate

There total 5 articles about methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-glycero-D-talo-non-2-en-onate (82159-65-7,82189-34-2) → methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate (82159-67-9)

Guidance literature:

With manganese(IV) oxide; In chloroform; at 25 ℃; for 4h;

DOI:10.1016/S0008-6215(00)80690-4

Reference yield: 83.0%

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-glycero-D-galacto-non-2-en-onate (82159-65-7,82189-34-2) → methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate (82159-67-9)

Guidance literature:

With manganese(IV) oxide; In chloroform; at 25 ℃; for 4h;

DOI:10.1016/S0008-6215(00)80690-4

Reference yield:

4,4'-dimethoxytrityl chloride (40615-36-9) → methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-manno-non-2-en-4-ulosonate (82159-67-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 71 percent / pyridine / 48 h / 25 °C

2: 83 percent / manganese dioxide / CHCl₃ / 4 h / 25 °C

With pyridine; manganese(IV) oxide; In chloroform;

DOI:10.1016/S0008-6215(00)80690-4

upstream raw materials:

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-glycero-D-talo-non-2-en-onate

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-9-O-bis(4-methoxyphenyl)phenyl-methyl-D-glycero-D-galacto-non-2-en-onate

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-D-glycero-D-galacto-non-2-enonate

4,4'-dimethoxytrityl chloride