trideuteriomethanesulfonyl-benzene

Base Information

• Chemical Name: trideuteriomethanesulfonyl-benzene
• CAS No.: 14132-13-9
• Molecular Formula: C₇H₈O₂S
• Molecular Weight: 159.181
• Mol file: 14132-13-9.mol

Synonyms:trideuteriomethanesulfonyl-benzene

Chemical Property of trideuteriomethanesulfonyl-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trideuteriomethanesulfonyl-benzene

There total 4 articles about trideuteriomethanesulfonyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

methylphenylsulfonate (3112-85-4) → trideuteriomethanesulfonyl-benzene (14132-13-9)

Guidance literature:

With water-d2; sodium hydroxide; at 110 ℃;

DOI:10.1016/j.tetlet.2017.12.074

Reference yield:

methyl-phenyl-thioether (100-68-5) + thioanisole-α,α,α-d3 (826-07-3) → ((methyl-d3)sulfinyl)benzene (35449-57-1) + racemic methyl phenyl sulfoxide (1193-82-4) + methylphenylsulfonate (3112-85-4) + trideuteriomethanesulfonyl-benzene (14132-13-9)

Guidance literature:

With oxygen; methylene blue; In methanol; Solvent; Mechanism; Irradiation;

DOI:10.1021/ol900140w

Reference yield:

thioanisole-α,α,α-d3 (826-07-3) → ((methyl-d3)sulfinyl)benzene (35449-57-1) + trideuteriomethanesulfonyl-benzene (14132-13-9)

Guidance literature:

With methyltrifluoromethyldioxirane; In dichloromethane; at 0 ℃; Product distribution; with different solvent, in the presence of phenylmethyl sulfoxide, in the presence of 1,1,1-trifluoropropanone-⁽¹⁸⁾O-hydrate, study of O transfer;

DOI:10.1016/0040-4039(96)00248-1

upstream raw materials:

thioanisole-α,α,α-d3

methyl-phenyl-thioether

sodium benzenesulfonate

methylphenylsulfonate

Downstream raw materials:

methylphenylsulfonate