phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside

Base Information

• Chemical Name: phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside
• CAS No.: 1060735-41-2
• Molecular Formula: C₃₄H₃₄O₆S
• Molecular Weight: 570.706
• Mol file: 1060735-41-2.mol

Synonyms:phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside

Chemical Property of phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
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MSDS Files:

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Technology Process of phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside

There total 1 articles about phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

C27H30O6S (1103735-85-8) + benzaldehyde dimethyl acetal (1125-88-8) → phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside (1060735-41-2)

Guidance literature:

With camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 14h; Inert atmosphere;

DOI:10.1021/jo801414c

Reference yield: 91.0%

phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside (1060735-41-2) + 2-bromomethylnaphthyl bromide (939-26-4) → phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-3-O-(2-naphthalenylmethyl)-D-glycero-1-thio-α-D-mannoheptopyranoside (902751-31-9)

Guidance literature:

phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-1-thio-α-D-mannoheptopyranoside; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; for 0.333333h; Cooling with ice;

2-bromomethylnaphthyl bromide; With tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 12.5h; Inert atmosphere; Darkness;

DOI:10.1021/jo801414c

upstream raw materials:

C₂₇H₃₀O₆S

benzaldehyde dimethyl acetal

Downstream raw materials:

phenyl 2,7-di-O-benzyl-4,6-O-benzylidene-3-O-(2-naphthalenylmethyl)-D-glycero-1-thio-α-D-mannoheptopyranoside