trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

Base Information

Chemical Name:trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2
CAS No.:647012-10-0
Molecular Formula:C₅₀H₅₈ClF₅P₂Pt
Molecular Weight:1046.48
Hs Code.:

trans-PtCl(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>(CH<sub>2</sub>)8CH=CH<sub>2</sub>)2

Synonyms:trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

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Chemical Property of trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

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Technology Process of trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

There total 1 articles about trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: {platinum(II)(μ-chloride)(pentafluorophenyl)(tetrahydrothiophene)}2

: 52007-40-6
(C₆H₅)2P(CH₂)8CHCH₂

: 647012-10-0
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

Guidance literature:: In dichloromethane; under N2; mixt. of (Pt(μ-Cl)(C6F5)(SC4H8))2 and phosphane in CH2Cl2 was stirred for 11 h; solvent removed in vacuo, chromy. (neutral alumina, CH2Cl2/hexane (1/1)), evapd. in vacuo; elem. anal.;
DOI:10.1021/om034121u

Reference yield: 95.0%

: 460-12-8,27987-87-7
Butadiyne

: 647012-10-0
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

: 945679-65-2
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)2H

Guidance literature:: With HN(C₂H₅)2; copper(l) iodide; In tetrahydrofuran; dichloromethane; diyne, HN(C2H5)2, CuI (cat.);
DOI:10.1021/ja071612n

Reference yield: 90.0%

: 647012-10-0
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

: 647840-62-8,647012-14-4
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH(CH₂)8PPh₂)

Guidance literature:: dichloro(tricyclohexylphosphino)(benzylidene)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)ruthenium(III); In dichloromethane; under N2; soln. of Pt complex and Ru catalyst in CH2Cl2 heated under reflux for 4 h; solvent removed in vacuo, CH2Cl2 added, soln. filtered through neutral alumina, filtrate evapd. in vacuo;
DOI:10.1021/om034121u