(+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane

Base Information

• Chemical Name: (+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane
• CAS No.: 1092556-14-3
• Molecular Formula: C₂₇H₄₆O₂SSi
• Molecular Weight: 462.813
• Mol file: 1092556-14-3.mol

Synonyms:(+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane

Chemical Property of (+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane

There total 1 articles about (+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tributylchlorosilane (995-45-9) + (+)-(6R,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol (1092556-52-9) → (+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane (1092556-14-3)

Guidance literature:

With dmap; triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 216h; Inert atmosphere;

DOI:10.1021/jo801803m

Reference yield: 92.0%

(+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane (1092556-14-3) → (-)-(6R)-(2E,4E)-[5-(p-tolylsulfonyl)octa-2,4-dien-6-yloxy]tributylsilane (1092556-71-2)

Guidance literature:

With magnesium bis(monoperoxyphthalate) hexahydrate; In methanol; at 0 - 20 ℃; for 7h; Inert atmosphere;

DOI:10.1021/jo801803m

Reference yield: 92.0%

(+)-(6R,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane (1092556-14-3) → C27H46O4SSi (1092556-77-8)

Guidance literature:

With (S,S)-(+)-N,N’-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride; ammonium acetate; dihydrogen peroxide; In methanol; dichloromethane; at 0 - 4 ℃; for 168h; optical yield given as %de; Inert atmosphere;

DOI:10.1021/jo801803m

upstream raw materials:

tributylchlorosilane

(+)-(6R,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol

Downstream raw materials:

(-)-(6R)-(2E,4E)-[5-(p-tolylsulfonyl)octa-2,4-dien-6-yloxy]tributylsilane

C₂₇H₄₆O₄SSi