((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane
CAS No.:1407163-75-0
Molecular Formula:C₂₀H₃₂Br₂O₂Si
Molecular Weight:492.366
Hs Code.:

Synonyms:((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Suppliers and Price of ((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

There total 10 articles about ((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1407163-74-9
(2S,5R)-2-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexanal

: 1407163-75-0
((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Guidance literature:: With carbon tetrabromide; triethylamine; triphenylphosphine; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1039/c2ob26396c

Reference yield:

: 1407163-73-8
(2S,5R)-2-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexan-1-ol

: 1407163-75-0
((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: Dess-Martin periodane / dichloromethane / 0.5 h / 0 - 20 °C

2: triethylamine; carbon tetrabromide; triphenylphosphine / dichloromethane / 3 h / 0 °C

With carbon tetrabromide; Dess-Martin periodane; triethylamine; triphenylphosphine; In dichloromethane;
DOI:10.1039/c2ob26396c

Reference yield:

: 3427-24-5
(2S,3E,5S)-1,2,5,6-tetrahydroxy-1,2:5,6-di-O-isopropylidene-hex-3-ene

: 1407163-75-0
((2R,5S)-5-(benzyloxy)-7,7-dibromohept-6-en-2-yloxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 10 steps

1: copper(II) choride dihydrate / acetonitrile / 0.5 h / 0 - 20 °C

2: 10% Pd/C; hydrogen / ethyl acetate / 4 h / 20 °C

3: di(n-butyl)tin oxide; triethylamine / dichloromethane / 0.5 h / 0 - 20 °C

4: lithium aluminium tetrahydride / tetrahydrofuran / 0.5 h / 0 - 20 °C

5: copper(II) choride dihydrate / acetonitrile / 0.5 h / 0 - 20 °C

6: camphor-10-sulfonic acid / dichloromethane / 5 h / 0 - 20 °C

7: 1H-imidazole / dichloromethane / 2 h / 0 - 20 °C

8: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -40 °C

9: Dess-Martin periodane / dichloromethane / 0.5 h / 0 - 20 °C

10: triethylamine; carbon tetrabromide; triphenylphosphine / dichloromethane / 3 h / 0 °C

With 1H-imidazole; lithium aluminium tetrahydride; copper(II) choride dihydrate; carbon tetrabromide; camphor-10-sulfonic acid; 10% Pd/C; hydrogen; diisobutylaluminium hydride; di(n-butyl)tin oxide; Dess-Martin periodane; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; ethyl acetate; toluene; acetonitrile;
DOI:10.1039/c2ob26396c