2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Base Information

Chemical Name:2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate
CAS No.:1359987-79-3
Molecular Formula:C₄₇H₃₈Cl₃NO₁₄
Molecular Weight:947.176
Hs Code.:

Synonyms:2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Suppliers and Price of 2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

There total 6 articles about 2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 1359987-98-6
phenyl 2,3,6-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-1-thio-α-L-arabinofuranoside

: 545-06-2
trichloroacetonitrile

: 1359987-79-3
2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Guidance literature:: phenyl 2,3,6-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-1-thio-α-L-arabinofuranoside; With N-Bromosuccinimide; In water; ethyl acetate; at 20 ℃; for 4h;

trichloroacetonitrile; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1021/jo300084g

Reference yield:

: 1359987-96-4
phenyl 2,5-di-O-benzoyl-3-O-tert-butyldiphenylsilyl-1-thio-α-L-arabinofuranoside

: 1359987-79-3
2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 - 15 °C / Inert atmosphere

2.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / 0 °C / Inert atmosphere; Molecular sieve

3.1: N-Bromosuccinimide / water; ethyl acetate / 4 h / 20 °C

3.2: 2 h / 0 - 20 °C / Inert atmosphere

With N-Bromosuccinimide; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; water; ethyl acetate;
DOI:10.1021/jo300084g

Reference yield:

: 1359987-97-5
phenyl 2,5-di-O-benzoyl-1-thio-α-L-arabinofuranoside

: 1359987-79-3
2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-2,5-di-O-benzoyl-α-L-arabinofuranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / 0 °C / Inert atmosphere; Molecular sieve

2.1: N-Bromosuccinimide / water; ethyl acetate / 4 h / 20 °C

2.2: 2 h / 0 - 20 °C / Inert atmosphere

With N-Bromosuccinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; water; ethyl acetate;
DOI:10.1021/jo300084g