(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

Base Information

Chemical Name:(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene
CAS No.:162084-24-4
Molecular Formula:C₁₉H₃₄O₂Si
Molecular Weight:322.563
Hs Code.:

Synonyms:(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

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Chemical Property of (+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

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Technology Process of (+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

There total 4 articles about (+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 106-96-7
propargyl bromide

: 168432-44-8
(+/-)-3-<<(tert-butyldimethylsilyl)oxy>methyl>-2,4,4-trimethylcyclohex-2-en-1-ol

: 162084-24-4
(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

Guidance literature:: With sodium hydroxide; tetra-(n-butyl)ammonium iodide; In toluene; at 20 ℃; for 17h;

Reference yield:

: 140887-86-1
(+/-)-3-(hydroxymethyl)-2,4,4-trimethylcyclohex-2-en-1-ol

: 162084-24-4
(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / imidazole / dimethylformamide / 0 deg C, 4 h; rt, overnight

2: 97 percent / 60percent aq. NaOH, Bu₄NI / toluene / 17 h / 20 °C

With 1H-imidazole; sodium hydroxide; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; toluene;

Reference yield:

: 60078-92-4,14393-38-5
2,4,4-trimethyl-3-formyl-2-cyclohexen-1-ol

: 162084-24-4
(+/-)-2-<<(tert-butyldimethylsilyl)oxy>methyl>-6-<(prop-2-ynyl)oxy>-1,3,3-trimethylcyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / NaBH₄ / methanol / 1 h / 0 °C

2: 61 percent / imidazole / dimethylformamide / 0 deg C, 4 h; rt, overnight

3: 97 percent / 60percent aq. NaOH, Bu₄NI / toluene / 17 h / 20 °C

With 1H-imidazole; sodium hydroxide; sodium tetrahydroborate; tetra-(n-butyl)ammonium iodide; In methanol; N,N-dimethyl-formamide; toluene;