((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane

Base Information

• Chemical Name: ((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane
• CAS No.: 765318-39-6
• Molecular Formula: C₂₆H₃₀O₂Si
• Molecular Weight: 402.609

Synonyms:((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane

Chemical Property of ((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of ((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane

There total 1 articles about ((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenylsilyl dichloride (80-10-4) → ((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane (765318-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 61 percent / n-BuLi / hexane; tetrahydrofuran / -78 - 20 °C

2: 77 percent / NaH / hexane / 0.33 h / 20 °C

With n-butyllithium; sodium hydride; In tetrahydrofuran; hexane;

DOI:10.1021/jo048908l

Reference yield:

((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(3-methoxy-prop-1-ynyl)-diphenyl-silane (765318-39-6) + 5-hexenyl acetate (5048-26-0) → (6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-(2-methoxymethyl-1-methylene-allyl)-diphenyl-silane + Acetic acid (Z)-6-[(6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-ylmethoxy)-diphenyl-silanyl]-7-methoxymethyl-octa-5,7-dienyl ester

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 40 ℃;

DOI:10.1021/ja0520159

upstream raw materials:

diphenylsilyl dichloride

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