(μ-H)Os3(CO)10(μ-SePh)

Base Information

• Chemical Name: (μ-H)Os3(CO)10(μ-SePh)
• CAS No.: 93503-79-8
• Molecular Formula: C₁₆H₆O₁₀Os₃Se
• Molecular Weight: 1007.78
• Mol file: 93503-79-8.mol

Synonyms:(μ-H)Os3(CO)10(μ-SePh)

Chemical Property of (μ-H)Os3(CO)10(μ-SePh)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (μ-H)Os3(CO)10(μ-SePh)

There total 1 articles about (μ-H)Os3(CO)10(μ-SePh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

bis(acetonitrile)decacarbonyltriosmium + Benzeneselenol (645-96-5) → (μ-H)Os3(CO)10(μ-SePh) (93503-79-8)

Guidance literature:

In dichloromethane; to a soln. of Os complex at room temp. under N2 was added via syringe PhSeH; stirring at room temp. for 4 h; evapn., , dissoln. in hexane, chromy. on silica gel (hexane), recrystn.from hexane;

Reference yield: 95.0%

(μ-H)Os3(CO)10(μ-SePh) (93503-79-8) → dodecacarbonyl triosmium (15696-40-9) + bis(η3-selenido)nonacarbonyltriosmium (72282-41-8)

Guidance literature:

With CO; In octane; byproducts: benzene; Irradiation (UV/VIS); heating to 160°C under 3000 psi CO for 6 h; the solvent was collected by distn. in vac. and photolyzed for 2 h at room temp. to give Os3(CO)12; residue was chromd. on silica gel (hexane/CH2Cl2); recrystn. from hexane;

upstream raw materials:

Benzeneselenol

Downstream raw materials:

dodecacarbonyl triosmium

bis(η3-selenido)nonacarbonyltriosmium