C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂

Base Information

• Chemical Name: C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂
• CAS No.: 132148-79-9
• Molecular Formula: C₂₄H₄₂OSn
• Molecular Weight: 465.307
• Mol file: 132148-79-9.mol

Synonyms:C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂

Chemical Property of C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂

Chemical Property:

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Technology Process of C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂

There total 1 articles about C₆H₅(CH₂)2CH(OH)CH(Sn(C₄H₉)3)CHCH₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-phenyl-propionaldehyde (104-53-0) + Li(1+)*[(CH3)3SiC9H15BH2](1-)*(C2H5)2O=Li[(CH3)3SiC9H15BH2]*(C2H5)2O + allenyltributylstannane (53915-69-8) → C6H5(CH2)2CH(OH)CH(Sn(C4H9)3)CHCH2 (132148-79-9)

Guidance literature:

With chloro-trimethyl-silane; In dichloromethane; Sn compd. reacted with B compd. and (CH3)3SiCl in CH2Cl2 at -10°Cfor 5 h, reacted with C6H5(CH2)2CHO at -78°C for 4 h; treated with ethanolamine; not isolated, detected by NMR; syn/anti ratioof 91/9;

DOI:10.1021/ja905494c

upstream raw materials:

3-phenyl-propionaldehyde

allenyltributylstannane