cis-Pt(succinimido)2(PPh₃)2

Base Information

• Chemical Name: cis-Pt(succinimido)2(PPh₃)2
• CAS No.: 102982-55-8
• Molecular Formula: C₄₄H₃₈N₂O₄P₂Pt
• Molecular Weight: 915.824
• Mol file: 102982-55-8.mol

Synonyms:cis-Pt(succinimido)2(PPh₃)2

Chemical Property of cis-Pt(succinimido)2(PPh₃)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cis-Pt(succinimido)2(PPh₃)2

There total 4 articles about cis-Pt(succinimido)2(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Succinimide (123-56-8,89963-74-6) + (hydroperoxo)(succinimido)bis(triphenylphosphino) platinum(II) (102982-52-5) → Pt(P(C6H5)3)2(NC(O)CH2CH2CO)2 (102982-55-8)

Guidance literature:

In benzene; byproducts: H2O2; N2-atmosphere; stirring (8 h); filtration, partial evapn., pptn. on hexane addn., filtration, washing (hexane), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(85)80356-9

Reference yield: 75.0%

Succinimide (123-56-8,89963-74-6) + Pt(O2C(O)O)(PPh3)2 (25908-23-0) → cis-Pt(succinimido)2(PPh3)2 (102982-55-8)

Guidance literature:

With carbon dioxide; In 1,2-dichloro-ethane; After 2 min bubbling CO2 through C2H4Cl2 the platinum complex and succinimide were added and the soln. heated at 55°C and stirred for 5 h.; concg., addn. of n-hexane, filtn., chrystn. from CH2Cl2/n-hexane, evapn. of the mother liquor to dryness, IR and (1)H-NMR of the residue;

DOI:10.1016/S0020-1693(00)80218-2

Reference yield: 68.0%

(hydroperoxo)(succinimido)bis(triphenylphosphino) platinum(II) (102982-52-5) → Pt(O2C(O)O)(PPh3)2 (25908-23-0) + cis-Pt(succinimido)2(PPh3)2 (102982-55-8)

Guidance literature:

With carbon dioxide; In 1,2-dichloro-ethane; After 2 min bubbling CO2 through C2H4Cl2 the platinum peroxide complex was added, the suspn. heated at 55°C and stirred for 4.5 h.; concg., addn. of n-hexane, filtn., washing with n-hexane, crystn. from CH2Cl2/diethylether, concg. of the mother liquors, addn. of CH2Cl2 and diethyl ether, filtn.; manipulations under N2;

DOI:10.1016/S0020-1693(00)80218-2

upstream raw materials:

Succinimide

Pt(O₂C(O)O)(PPh₃)2

(hydroperoxo)(succinimido)bis(triphenylphosphino) platinum(II)

dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Refernces