3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

Base Information

Chemical Name:3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester
CAS No.:288143-56-6
Molecular Formula:C₁₉H₂₇ClO₇
Molecular Weight:402.872
Hs Code.:

Synonyms:3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

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Technology Process of 3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

There total 1 articles about 3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 63024-77-1
3-(Chloromethyl)benzoyl chloride

: 75507-25-4,80004-03-1
2-(hydroxymethyl)-15-crown-5

: 288143-56-6
3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; 4 A molecular sieve; In tetrahydrofuran; dichloromethane; at -78 - 20 ℃; for 21.5h;
DOI:10.1006/bioo.1999.1167

Reference yield:

: 288143-56-6
3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

: 3-[(4-hydroxybut-2-ynyl)sulfonylmethyl]benzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: ethanol / Heating

2: 0.277 g / nBuNH₂ / ethanol / 0 - 20 °C

3: 83 percent / iPr₂NEt / ethanol / 20 °C

4: 78 percent / oxone; potassium citrate buffer / methanol; H₂O / 0 - 20 °C / pH 5.5

With Oxone; potassium citrate buffer; N-butylamine; N-ethyl-N,N-diisopropylamine; In methanol; ethanol; water; 1: Substitution / 2: Elimination / 3: Alkylation / 4: Oxidation;
DOI:10.1006/bioo.1999.1167

Reference yield:

: 288143-56-6
3-chloromethylbenzoic acid 1,4,7,10,13-pentaoxacyclopentadec-2-ylmethyl ester

: 288143-66-8
Malonic acid bis-{4-[3-(1,4,7,10,13-pentaoxa-cyclopentadec-2-ylmethoxycarbonyl)-benzylsulfanyl]-but-2-ynyl} ester

Guidance literature:: Multi-step reaction with 4 steps

1: ethanol / Heating

2: 0.277 g / nBuNH₂ / ethanol / 0 - 20 °C

3: 83 percent / iPr₂NEt / ethanol / 20 °C

4: 26 percent / DMAP; iPr₂NEt / tetrahydrofuran / 13 h / Heating

With dmap; N-butylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; 1: Substitution / 2: Elimination / 3: Alkylation / 4: Esterification;
DOI:10.1006/bioo.1999.1167