(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

Base Information

Chemical Name:(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol
CAS No.:1322762-82-2
Molecular Formula:C₂₆H₃₆O₄S
Molecular Weight:444.635
Hs Code.:

Synonyms:(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

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Chemical Property of (2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

Chemical Property:

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Technology Process of (2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

There total 6 articles about (2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1322762-87-7
(Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-one

: 1322762-82-2
(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; toluene; at -78 ℃; for 1h; diastereoselective reaction;
DOI:10.1002/chem.201003666

Reference yield:

: C₂₂H₃₅BO₂

: 1322762-82-2
(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; 1,4-dioxane / 8 h / 85 °C / Inert atmosphere

2.1: lithium diisopropyl amide / tetrahydrofuran; hexanes / 0.5 h / -40 °C

2.2: 1 h / 0 °C

3.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 1 h / -78 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; 1,4-dioxane; hexanes; toluene; 1.1: Suzuki coupling;
DOI:10.1002/chem.201003666

Reference yield:

: 1322762-84-4
(Z)-ethyl 8-(4-methoxybenzyloxy)-3,7-dimethyloct-2-enoate

: 1322762-82-2
(2S,Z)-9-(4-methoxybenzyloxy)-4,8-dimethyl-1-[(Rs)-(p-tolylsulfinyl)]non-3-en-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium diisopropyl amide / tetrahydrofuran; hexanes / 0.5 h / -40 °C

1.2: 1 h / 0 °C

2.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 1 h / -78 °C

With diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; hexanes; toluene;
DOI:10.1002/chem.201003666