phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside
CAS No.:95084-13-2
Molecular Formula:C₆₇H₆₈O₁₀S
Molecular Weight:1065.34
Hs Code.:

Synonyms:phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

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Chemical Property of phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

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Technology Process of phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

There total 17 articles about phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 38184-10-0
phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside

: 87470-73-3,120403-26-1,38184-12-2
phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 95084-13-2,95084-12-1
phenylthio-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside; With N-methylmaleimide; trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -78 ℃; for 0.0833333h; Molecular sieve; Inert atmosphere;

With tetra-(n-butyl)ammonium iodide; In dichloromethane; at -78 ℃; for 0.166667h;

phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside; In 1,4-dioxane; dichloromethane; at -78 - 20 ℃; for 40h;

Reference yield: 50.0%

: 74666-83-4,105990-37-2,125354-46-3,125354-47-4,125411-99-6,108739-67-9
1-deoxy-1-(S-ethyl)-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

: 87470-73-3,120403-26-1,38184-12-2
phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 95084-13-2
phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside; In acetonitrile; for 0.5h; Molecular sieve;

1-deoxy-1-(S-ethyl)-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside; With mesitylenesulfonylhydroxylamine; copper(II) bis(trifluoromethanesulfonate); In acetonitrile; at 20 ℃; Molecular sieve;
DOI:10.1021/acs.orglett.7b02886

Reference yield:

: 4196-35-4
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide

: 87470-73-3,120403-26-1,38184-12-2
phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 95084-13-2,95084-12-1
phenylthio-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

: 95084-13-2
phenyl 6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; 4,7-Dipiperidino-1,10-phenanthroline; In dichloromethane; at 25 ℃; for 24h; Overall yield = 89 percent; Inert atmosphere;
DOI:10.1002/adsc.202100639