phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside

Base Information

• Chemical Name: phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside
• CAS No.: 124718-63-4
• Molecular Formula: C₃₉H₃₈O₅S
• Molecular Weight: 618.794
• Mol file: 124718-63-4.mol

Synonyms:phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside

Chemical Property of phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

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Technology Process of phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside

There total 3 articles about phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4,6-tri-O-benzyl-D-glucal (55628-54-1) + phenylbis(thiophenyl)sulfonium hexachloroantimonate → phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-α-D-mannopyranoside (124718-64-5) + phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside (124718-63-4) + 3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranose (117901-42-5) + 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucose (136174-91-9)

Guidance literature:

With tributyltin phenoxide; In dichloromethane; at -60 ℃; for 0.166667h;

DOI:10.1021/jo00033a033

Reference yield:

3,4,6-tri-O-benzyl-D-glucal (55628-54-1) + tributyltin phenoxide (3587-18-6) → phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-α-D-mannopyranoside (124718-64-5) + phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside (124718-63-4)

Guidance literature:

In dichloromethane; at -60 ℃; Yield given. Yields of byproduct given;

DOI:10.1021/jo00288a003

Reference yield:

3,4,6-tri-O-benzyl-D-glucal (55628-54-1) + tributyltin phenoxide (3587-18-6) + phenylbis(thiophenyl)sulfonium hexachloroantimonate → phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-α-D-mannopyranoside (124718-64-5) + phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucopyranoside (124718-63-4) + 3,4,6-Tri-O-benzyl-2-deoxy-2-phenylthio-α-D-glucopyranose (117901-42-5) + 3,4,6-tri-O-benzyl-2-deoxy-2-(phenylthio)-β-D-glucose (136174-91-9)

Guidance literature:

In dichloromethane; at -60 ℃; for 0.166667h;

DOI:10.1021/jo00033a033

upstream raw materials:

3,4,6-tri-O-benzyl-D-glucal

tributyltin phenoxide

Downstream raw materials:

phenyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside