phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Base Information

Chemical Name:phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside
CAS No.:1644133-96-9
Molecular Formula:C₅₃H₄₆O₁₃S
Molecular Weight:923.006
Hs Code.:

Synonyms:phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Suppliers and Price of phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

There total 8 articles about phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 2,3,4-tri-O-benzoyl-D-rhamnopyranosyl trichloroacetimidate

: 1644133-94-7
phenyl-2,4-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

: 1644133-96-9
phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Guidance literature:: 2,3,4-tri-O-benzoyl-D-rhamnopyranosyl trichloroacetimidate; phenyl-2,4-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside; In dichloromethane; at 20 ℃; for 0.25h; Molecular sieve; Inert atmosphere;

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -50 ℃; for 2h;
DOI:10.3762/bjoc.10.153

Reference yield:

: 159407-19-9
phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 1644133-96-9
phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: camphor-10-sulfonic acid / acetonitrile / 0 - 20 °C

1.2: 25 °C

2.1: di-tert-butyl peroxide; triisopropylsilanethiol / octane / 2 h / Reflux; Inert atmosphere

3.1: dichloromethane / 0.25 h / 20 °C / Molecular sieve; Inert atmosphere

3.2: 2 h / -50 °C

With di-tert-butyl peroxide; camphor-10-sulfonic acid; triisopropylsilanethiol; In octane; dichloromethane; acetonitrile;
DOI:10.3762/bjoc.10.153

Reference yield:

: phenyl-2,3-di(O-benzoyl)-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 1644133-96-9
phenyl-2,3,4-tri(O-benzoyl)-α-D-rhamnopyranosyl-(1→3)-2',4'-di(O-benzoyl)-1-thio-α-D-rhamnopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: di-tert-butyl peroxide; triisopropylsilanethiol / octane / 2 h / Reflux; Inert atmosphere

2.1: trichloroisocyanuric acid / water; acetone / 0.75 h / 20 °C

3.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane

4.1: dichloromethane / 0.25 h / 20 °C / Molecular sieve; Inert atmosphere

4.2: 2 h / -50 °C

With di-tert-butyl peroxide; trichloroisocyanuric acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triisopropylsilanethiol; In octane; dichloromethane; water; acetone;
DOI:10.3762/bjoc.10.153