(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

Base Information

Chemical Name:(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal
CAS No.:864914-93-2
Molecular Formula:C₂₄H₃₂O₃Si
Molecular Weight:396.602
Hs Code.:

Synonyms:(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

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Chemical Property of (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

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Technology Process of (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

There total 3 articles about (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 864915-12-8
(E)-(2R,3S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-5-methyl-hept-4-ene-1,2-diol

: 864914-93-2
(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

Guidance literature:: With sodium periodate; In methanol;
DOI:10.1016/j.tetlet.2005.06.133

Reference yield:

: tert-Butyl-[(E)-(S)-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-methoxy-3-methyl-pent-3-enyloxy]-diphenyl-silane

: 864914-93-2
(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / aq. AcOH / tetrahydrofuran

2: 94 percent / NaIO₄ / aq. methanol

With sodium periodate; acetic acid; In tetrahydrofuran; methanol;
DOI:10.1016/j.tetlet.2005.06.133

Reference yield:

: 148583-99-7
(E)-(tert-butyl)(4-iodo-3-methylbut-3-enyloxy)diphenylsilane

: 864914-93-2
(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-hex-3-enal

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi; (i-PrO)2TiCl₂

1.2: diethyl ether / -78 - 0 °C

1.3: 84 percent / NaH / tetrahydrofuran

2.1: 83 percent / aq. AcOH / tetrahydrofuran

3.1: 94 percent / NaIO₄ / aq. methanol

With sodium periodate; n-butyllithium; titanium(IV) dichlorodiisopropylate; acetic acid; In tetrahydrofuran; methanol;
DOI:10.1016/j.tetlet.2005.06.133