C₃₆H₄₇NO₃Si

Base Information

• Chemical Name: C₃₆H₄₇NO₃Si
• CAS No.: 880152-45-4
• Molecular Formula: C₃₆H₄₇NO₃Si
• Molecular Weight: 569.86
• Mol file: 880152-45-4.mol

Synonyms:C₃₆H₄₇NO₃Si

Chemical Property of C₃₆H₄₇NO₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₄₇NO₃Si

There total 16 articles about C₃₆H₄₇NO₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C36H45NO3Si (880152-36-3) → C36H47NO3Si (880152-45-4)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethyl acetate; at 20 ℃; for 4h; under 760 Torr;

DOI:10.1021/ol053059p

Reference yield:

4-bromo-6-butyl-2-pyrone (880152-32-9) → C36H47NO3Si (880152-45-4)

Guidance literature:

Multi-step reaction with 5 steps

1: 61 percent / pyridine / ethanol / 48 h / Heating

2: K₂CO₃ / methanol; H₂O / 1 h / 20 °C

3: 504.0 mg / N-methylmorpholine-N-oxide; TPAP; 4 Angstroem molecular sieves / CH₂Cl₂ / 1 h / 20 °C

4: 68 percent / Na₂SO₄; piperidinium acetate / ethyl acetate; toluene / Heating

5: 90 percent / H₂ / 10 percent Pd/C / ethyl acetate / 4 h / 20 °C / 760 Torr

With pyridine; tetrapropylammonium perruthennate; 4 A molecular sieve; hydrogen; piperdinium acetate; potassium carbonate; 4-methylmorpholine N-oxide; sodium sulfate; 10% palladium on active carbon; In methanol; ethanol; dichloromethane; water; ethyl acetate; toluene;

Reference yield:

[1-(tert-butyl-diphenyl-silanyloxymethyl)-3-(2-hydroxymethyl-cyclohex-1-enyl)-propyl]-carbamic acid tert-butyl ester (880152-31-8) → C36H47NO3Si (880152-45-4)

Guidance literature:

Multi-step reaction with 7 steps

1: pyridine / 20 °C

2: 100 percent / TFA / CH₂Cl₂ / 1 h / 0 °C

3: 61 percent / pyridine / ethanol / 48 h / Heating

4: K₂CO₃ / methanol; H₂O / 1 h / 20 °C

5: 504.0 mg / N-methylmorpholine-N-oxide; TPAP; 4 Angstroem molecular sieves / CH₂Cl₂ / 1 h / 20 °C

6: 68 percent / Na₂SO₄; piperidinium acetate / ethyl acetate; toluene / Heating

7: 90 percent / H₂ / 10 percent Pd/C / ethyl acetate / 4 h / 20 °C / 760 Torr

With pyridine; tetrapropylammonium perruthennate; 4 A molecular sieve; hydrogen; piperdinium acetate; potassium carbonate; 4-methylmorpholine N-oxide; sodium sulfate; trifluoroacetic acid; 10% palladium on active carbon; In methanol; ethanol; dichloromethane; water; ethyl acetate; toluene;

upstream raw materials:

C₃₆H₄₅NO₃Si

4-bromo-6-butyl-2-pyrone

2-(3-tert-butoxycarbonylamino-4-hydroxy-butyl)-cyclohex-1-enecarboxylic acid ethyl ester

4-[2-(2-ethoxycarbonyl-cyclohex-1-enyl)-ethyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester