3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide

Base Information

• Chemical Name: 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide
• CAS No.: 133900-25-1
• Molecular Formula: C₁₅H₁₅BrF₃NO₄
• Molecular Weight: 410.188
• Mol file: 133900-25-1.mol

Synonyms:3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide

Chemical Property of 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide

Chemical Property:

Purity/Quality:

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Technology Process of 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide

There total 1 articles about 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-O-acetyl-3-O-benzoyl-2,4,6-tridesoxy-4-trifluoroacetamido-β-L-lyxo-hexopyranoside (90520-32-4) → 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide (133900-25-1)

Guidance literature:

With hydrogen bromide; In benzene; for 0.0833333h; Ambient temperature;

DOI:10.1021/jm00062a008

Reference yield: 94.0%

3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide (133900-25-1) → (S)-cis-1-O-(3-O-benzoyl-2,4,6-trideoxy-4-(trifluoroacetamido)-α-L-lyxo-hexopyranosyl)-1,2,3,4,6,11-hexahydro-1,3,5,12-tetrahydroxy-3-(hydroxymethyl)-3,13-O-isopropylidene-6,11-naphthacenedione

Guidance literature:

With 4 A molecular sieve; mercury dibromide; mercury(II) oxide; In dichloromethane; for 18h; Ambient temperature;

DOI:10.1021/jm00062a008

Reference yield: 60.0%

(S)-cis-1,2,3,4,6,11-hexahydro-1,3,5,12-tetrahydroxy-3-methylnaphthacene-6,11-quinone (78548-50-2) + 3-O-Benzoyl-4-trifluoroacetamido-2,4,6-trideoxy-L-hexopyranose bromide (133900-25-1) → Benzoic acid (2S,3R,4S)-2-methyl-3-(2,2,2-trifluoro-acetylamino)-6-((1S,3S)-3,5,12-trihydroxy-3-methyl-6,11-dioxo-1,2,3,4,6,11-hexahydro-naphthacen-1-yloxy)-tetrahydro-pyran-4-yl ester

Guidance literature:

With 4 A molecular sieve; mercury dibromide; mercury(II) oxide; In dichloromethane;

DOI:10.7164/antibiotics.48.1185

upstream raw materials:

1-O-acetyl-3-O-benzoyl-2,4,6-tridesoxy-4-trifluoroacetamido-β-L-lyxo-hexopyranoside