bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

Base Information

Chemical Name:bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium
CAS No.:264145-50-8
Molecular Formula:C₅₄H₄₅BrP₂Pd
Molecular Weight:942.223
Hs Code.:

Synonyms:bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

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Chemical Property of bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

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Technology Process of bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

There total 1 articles about bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 176780-03-3,164927-39-3
(Pd[P(o-tolyl)3](4-(t)Bu-C6H4)(μ-Br))2

: 76144-87-1,76189-55-4,76189-56-5,136655-44-2,98327-87-8
2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl

: 264145-50-8
bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

Guidance literature:: In benzene; under N2; suspn. of ligand (2 equiv.) in benzene added dropwise to stirred soln. of Pd complex in benzene; stirred at room temp. for 2 h; solvent removed in vac.; dissolved in toluene; layered with ether; cooled at -35°C;
DOI:10.1021/om049726k

Reference yield: 56.1%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 264145-50-8
bromo(4-tert-butylphenyl)(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium

: 75782-32-0
potassium salt of phenylacetonitrile

: [Pd(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(CH(Ph)CN)(4-tert-butylphenyl)]*(THF)

Guidance literature:: In toluene; under N2; mixt. of Pd complex and K compd. (molar ratio 1:2) suspended in toluene; stirred at room temp. for 1 h; filtered through Celite; filtrate concd.; layered with pentane at -35°C; recrystd. from THF soln. layered with ether at -35°C; elem. anal.;
DOI:10.1021/om049726k