3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile

Base Information

• Chemical Name: 3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile
• CAS No.: 345922-09-0
• Molecular Formula: C₂₇H₂₈NOP
• Molecular Weight: 413.499
• Mol file: 345922-09-0.mol

Synonyms:3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile

Chemical Property of 3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile

Chemical Property:

Purity/Quality:

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Technology Process of 3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile

There total 1 articles about 3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-nonanenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

oenanthic acid (111-14-8) + cyanomethylene triphenylphosphorane (16640-68-9) → 3-oxo-2-(triphenyl-λ5-phosphanylidene)-nonanenitrile (345922-09-0)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 5h;

DOI:10.1021/jo0015974

Reference yield: 81.0%

benzylamine (100-46-9) + 3-oxo-2-(triphenyl-λ5-phosphanylidene)-nonanenitrile (345922-09-0) → N-benzyl-2-oxooctanamide

Guidance literature:

With 3,3-dimethyldioxirane; In dichloromethane; acetone; at -78 ℃; for 0.0833333h;

DOI:10.1021/jo0015974

upstream raw materials:

oenanthic acid

cyanomethylene triphenylphosphorane