1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

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Chemical Name:1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene
CAS No.:479213-75-7
Molecular Formula:C₂₈H₃₃Br₃O₉
Molecular Weight:753.277
Hs Code.:

Synonyms:1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

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Chemical Property of 1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

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Technology Process of 1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

There total 3 articles about 1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 40637-56-7
dimethyl allylmalonate

: 479213-71-3
1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(bromomethyl)benzene

: 479213-75-7
1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

Guidance literature:: dimethyl allylmalonate; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.5h;

1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(bromomethyl)benzene; In tetrahydrofuran; at 20 ℃; for 9.5h; Further stages.;
DOI:10.1021/jo0258094

Reference yield:

: 608-72-0
2,4,6-tribromomesitylene

: 479213-75-7
1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 64 percent / N-bromosuccinimide; BPO / CCl₄ / 4 h / Heating

2.1: NaH / tetrahydrofuran; various solvent(s) / 0.33 h / 20 °C

2.2: 29 percent / tetrahydrofuran; various solvent(s) / 4.5 h / 20 °C

3.1: NaH / tetrahydrofuran; various solvent(s) / 0.5 h / 20 °C

3.2: 68 percent / tetrahydrofuran; various solvent(s) / 9.5 h / 20 °C

With N-Bromosuccinimide; sodium hydride; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane;
DOI:10.1021/jo0258094

Reference yield:

: 29165-34-2
1,3,5-tris(bromo)-2,4,6-tris(bromomethyl) benzene

: 479213-75-7
1,3,5-tribromo-2-(allyloxymethyl)-4,6-bis(2',2'-bis(methoxycarbonyl)pent-4'-enyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran; various solvent(s) / 0.33 h / 20 °C

1.2: 29 percent / tetrahydrofuran; various solvent(s) / 4.5 h / 20 °C

2.1: NaH / tetrahydrofuran; various solvent(s) / 0.5 h / 20 °C

2.2: 68 percent / tetrahydrofuran; various solvent(s) / 9.5 h / 20 °C

With sodium hydride; In tetrahydrofuran;
DOI:10.1021/jo0258094