5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

Base Information

Chemical Name:5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)
CAS No.:1430223-58-7
Molecular Formula:C₄₇H₄₁BN₄O₅Zn
Molecular Weight:818.067
Hs Code.:

Synonyms:5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

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Chemical Property of 5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

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Technology Process of 5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

There total 3 articles about 5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1430223-56-5
20-bromo-5,10,15-tris(p-methoxyphenyl)porphinatozinc(II)

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1430223-58-7
5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In 1,2-dichloro-ethane; at 85 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.201203033

Reference yield:

: 5,10,20-tris(4-methoxyphenyl)porphyrin

: 1430223-58-7
5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine; N-Bromosuccinimide / chloroform / 0.5 h / 0 °C / Inert atmosphere

2: zinc acetate hydrate / chloroform; methanol / 20 °C / Reflux

3: triethylamine; bis-triphenylphosphine-palladium(II) chloride / 1,2-dichloro-ethane / 2 h / 85 °C / Inert atmosphere

With pyridine; bis-triphenylphosphine-palladium(II) chloride; N-Bromosuccinimide; zinc acetate hydrate; triethylamine; In methanol; chloroform; 1,2-dichloro-ethane; 3: |Suzuki Coupling;
DOI:10.1002/chem.201203033

Reference yield:

: 5-bromo-10,15,20-tris(4-methoxyphenyl)porphyrin

: 1430223-58-7
5,10,15-tris(p-methoxyphenyl)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: zinc acetate hydrate / chloroform; methanol / 20 °C / Reflux

2: triethylamine; bis-triphenylphosphine-palladium(II) chloride / 1,2-dichloro-ethane / 2 h / 85 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; zinc acetate hydrate; triethylamine; In methanol; chloroform; 1,2-dichloro-ethane; 2: |Suzuki Coupling;
DOI:10.1002/chem.201203033