4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

Base Information

Chemical Name:4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole
CAS No.:142075-62-5
Molecular Formula:C₃₄H₆₁NO₄Si₃
Molecular Weight:632.119
Hs Code.:

Synonyms:4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

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Chemical Property of 4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

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Technology Process of 4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

There total 6 articles about 4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 142075-79-4
(S)-4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-4,5-dihydro-oxazole

: 142075-62-5
4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In benzene; Heating;
DOI:10.1016/S0040-4039(00)79046-0

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 142075-62-5
4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

Guidance literature:: Multi-step reaction with 2 steps

1: 2) Et₃N / 1) THF, -78 deg C, 2)CH₂Cl₂, -15 deg C

2: 100 percent / 2,3-dichloro-5,6-dicyanoquinone / benzene / Heating

With triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In benzene;
DOI:10.1016/S0040-4039(00)79046-0

Reference yield:

: 89922-82-7
3-(tert-butyldimethylsilanyloxy)propionaldehyde

: 142075-62-5
4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole

Guidance literature:: Multi-step reaction with 4 steps

1: 1) LiNEt₂ / 1) THF, -78 deg C, 2) -78 deg C

2: 1) Et₃N, 2) DIBAL / 1) CH₂Cl₂, -78 deg C, 2) CH₂Cl₂, -78 deg C

3: 2) Et₃N / 1) THF, -78 deg C, 2)CH₂Cl₂, -15 deg C

4: 100 percent / 2,3-dichloro-5,6-dicyanoquinone / benzene / Heating

With lithium diethylamide; diisobutylaluminium hydride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In benzene;
DOI:10.1016/S0040-4039(00)79046-0