(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

Base Information

Chemical Name:(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one
CAS No.:792959-80-9
Molecular Formula:C₄₉H₉₆O₅Si₄
Molecular Weight:877.64
Hs Code.:

(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

Synonyms:(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

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Chemical Property of (S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

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Technology Process of (S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

There total 11 articles about (S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 792959-79-6
(1R,3aR,7aR)-7a-methyl-1-[(S)-5-methyl-1-(4-methyl-4-trimethylsilanyloxy-pentyl)-4-oxo-5-trimethylsilanyloxy-hexyl]-octahydro-inden-4-one

: 139356-39-1
(1R,3R)-1,3-bis((tert-butyldimethyl)silanyloxy)-5-[2-(diphenylphosphinoyl)-ethylidene]cyclohexane

: 792959-80-9
(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

Guidance literature:: (1R,3R)-1,3-bis((tert-butyldimethyl)silanyloxy)-5-[2-(diphenylphosphinoyl)-ethylidene]cyclohexane; With n-butyllithium; In tetrahydrofuran; hexane; at -70 ℃; for 0.166667h;

(1R,3aR,7aR)-7a-methyl-1-[(S)-5-methyl-1-(4-methyl-4-trimethylsilanyloxy-pentyl)-4-oxo-5-trimethylsilanyloxy-hexyl]-octahydro-inden-4-one; In tetrahydrofuran; hexane; at -70 ℃; for 3.41667h;

Reference yield:

: 713521-72-3
(R)-2-[(1R,3aR,4S,7aR)-4-(tert-butyldimethylsilanyloxy)-7a-methyloctahydroinden-1-yl]-6-methylheptane-1,6-diol

: 792959-80-9
(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

Guidance literature:: Multi-step reaction with 10 steps

1.1: tributylphosphine / pyridine

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2.67 h / 0 - 20 °C

3.1: 1H-imidazole / N,N-dimethyl-formamide / 17 h

4.1: n-butyllithium / tetrahydrofuran; hexane / 5 h / -20 - -10 °C

5.1: methanol; magnesium / 2.67 h

6.1: N-chloro-succinimide; dimethylsulfide / toluene / 2.67 h / -30 - 0 °C

6.2: 0.17 h / -20 - -17 °C

7.1: fluorosilicic acid / acetonitrile / 3 h

8.1: pyridinium dichromate / dichloromethane / 3 h

9.1: tetrahydrofuran; cyclohexane / 10 h

10.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -70 °C

10.2: 3.42 h

With 1H-imidazole; methanol; N-chloro-succinimide; n-butyllithium; fluorosilicic acid; pyridinium dichromate; dimethylsulfide; tributylphosphine; magnesium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; pyridine; hexane; dichloromethane; cyclohexane; N,N-dimethyl-formamide; toluene; acetonitrile;

Reference yield:

: 792959-74-1
(S)-6-[(1R,3aR,4S,7aR)-4-(tert-butyl-dimethyl-silanyloxy)-7a-methyl-octahydro-inden-1-yl]-2,10-dihydroxy-2,10-dimethyl-undecan-3-one

: 792959-80-9
(S)-6-((1R,3aS,7aR)-4-{2-[(R)-3-((R)-tert-butyldimethylsilanyloxy)-5-(tert-butyldimethylsilanyloxy)-cyclohexylidene]-ethylidene}-7a-methyloctahydroinden-1-yl)-2,10-dimethyl-2,10-bis-trimethylsilanyloxyundecan-3-one

Guidance literature:: Multi-step reaction with 4 steps

1.1: fluorosilicic acid / acetonitrile / 3 h

2.1: pyridinium dichromate / dichloromethane / 3 h

3.1: tetrahydrofuran; cyclohexane / 10 h

4.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -70 °C

4.2: 3.42 h

With n-butyllithium; fluorosilicic acid; pyridinium dichromate; In tetrahydrofuran; hexane; dichloromethane; cyclohexane; acetonitrile;