μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate

Base Information

• Chemical Name: μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate
• CAS No.: 90554-89-5
• Molecular Formula: C₉₂H₆₈N₈O₃Ru₂*2H₂O
• Molecular Weight: 1571.77
• Mol file: 90554-89-5.mol

Synonyms:μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate

Chemical Property of μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate

There total 1 articles about μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethoxo(meso-tetraphenylporphyrinato)(ethanol)ruthenium(III) (90584-10-4) → μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate (90554-89-5)

Guidance literature:

With O₂; In dichloromethane;

DOI:10.1021/ja00330a020

Reference yield: 98.0%

μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate (90554-89-5) → μ-oxo-bis[chloro(meso-tetraphenylporphyrinato)ruthenium(IV)] (90554-91-9)

Guidance literature:

With HCl; In ethanol; dichloromethane; The soln. of reagents was heated under reflux for 10 min;; crystals were washed with EtOH, dried in vac. at 140°C; elem. anal.;;

DOI:10.1021/ja00330a020

Reference yield: 98.0%

μ-oxo-bis[ethoxo(meso-tetraphenylporphyrinato)ruthenium(IV)] dihydrate (90554-89-5) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → μ-oxo-bis[(o-hydroxyphenoxo)(meso-tetraphenylporphyrinato)ruthenium(IV)] (90554-90-8)

Guidance literature:

In ethanol; dichloromethane; The soln. of reagents was heated under reflux for 10 min then allowed to stand at room temp.;; crystals were washed with EtOH, dried in vac. at 140°C; elem. anal.;;

DOI:10.1021/ja00330a020

upstream raw materials:

ethoxo(meso-tetraphenylporphyrinato)(ethanol)ruthenium(III)

Downstream raw materials:

μ-oxo-bis[bromo(meso-tetraphenylporphyrinato)ruthenium(IV)]

(meso-tetraphenylporphyrinato)bis(tetrahydrofuran)ruthenium(II)

μ-oxo-bis[chloro(meso-tetraphenylporphyrinato)ruthenium(IV)]

μ-oxo-bis[(meso-tetraphenylporphyrinato)(trifluoroacetato)ruthenium(IV)]