(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Base Information

Chemical Name:(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane
CAS No.:89387-68-8
Molecular Formula:C₅₀H₅₄O₁₀
Molecular Weight:814.973
Hs Code.:

(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Synonyms:(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

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Chemical Property of (1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

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Technology Process of (1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

There total 1 articles about (1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 53081-30-4
tetra-O-benzyl-α-D-galactosyl bromide

: 78286-06-3
2-O-allyl-1,6-anhydro-4-O-benzyl-β-D-galactopyranose

: 89387-68-8
(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Guidance literature:: With 4 A molecular sieve; tetraethylammonium bromide; In dichloromethane; N,N-dimethyl-formamide; for 72h; Ambient temperature;
DOI:10.1016/0008-6215(84)85392-6

Reference yield: 80.0%

: 89387-68-8
(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

: 89387-69-9
(1R,2S,3S,4R,5R)-2-Benzyloxy-4-[((E)-propenyl)oxy]-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; Wilkinson's catalyst; In ethanol; for 3h; Heating;
DOI:10.1016/0008-6215(84)85392-6

Reference yield:

: 89387-68-8
(1R,2S,3S,4R,5R)-4-Allyloxy-2-benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octane

: 89387-70-2
(1R,2S,3R,4R,5R)-2-Benzyloxy-3-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-6,8-dioxa-bicyclo[3.2.1]octan-4-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / tris(triphenylphosphine)rhodium(I) chloride, diazabicyclo<2.2.2>octane / aq. ethanol / 3 h / Heating

2: 72 percent / mercuric oxide, mercuric chloride, H₂O / acetone / 0.17 h

With 1,4-diaza-bicyclo[2.2.2]octane; Wilkinson's catalyst; water; mercury dichloride; mercury(II) oxide; In ethanol; acetone;
DOI:10.1016/0008-6215(84)85392-6