C₄₇H₆₁NO₈Si

Base Information

Chemical Name:C₄₇H₆₁NO₈Si
CAS No.:1379449-92-9
Molecular Formula:C₄₇H₆₁NO₈Si
Molecular Weight:796.089
Hs Code.:

C<sub>47</sub>H<sub>61</sub>NO<sub>8</sub>Si

Synonyms:C₄₇H₆₁NO₈Si

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Chemical Property of C₄₇H₆₁NO₈Si

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Technology Process of C₄₇H₆₁NO₈Si

There total 10 articles about C₄₇H₆₁NO₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: (CH₃)3SnC₆H₃(OCH₃)C₆H₆(O)C₂H₄OSi(CH₃)2C(CH₃)3

: 1379449-79-2
C₂₇H₃₀F₃NO₈S

: 1379449-92-9
C₄₇H₆₁NO₈Si

Guidance literature:: With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; In N,N-dimethyl-formamide; at 45 ℃; for 16h; Inert atmosphere;
DOI:10.1021/ja301326k

Reference yield:

: 1379449-94-1
C₂₁H₃₂N₂O₆

: 1379449-92-9
C₄₇H₆₁NO₈Si

Guidance literature:: Multi-step reaction with 6 steps

1: tetrahydrofuran / -78 - 0 °C / Inert atmosphere

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 12 h / 25 °C

3: tetrahydrofuran / 0 - 25 °C / Inert atmosphere; Molecular sieve

4: pyridinium chlorochromate / dichloromethane / 4 h / 25 °C / Inert atmosphere; Molecular sieve

5: 2,6-di-tert-butyl-pyridine / nitromethane / 2 h / -20 °C / Inert atmosphere; Molecular sieve

6: copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Tetrabutylammoniumsalz der Diphenylphosphinsaeure / N,N-dimethyl-formamide / 16 h / 45 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-pyridine; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; pyridinium chlorochromate; In tetrahydrofuran; nitromethane; dichloromethane; N,N-dimethyl-formamide; 5: Friedel Crafts acylation / 6: Stille coupling;
DOI:10.1021/ja301326k

Reference yield:

: 1379449-81-6
C₁₈H₂₈N₂O₆

: 1379449-92-9
C₄₇H₆₁NO₈Si

Guidance literature:: Multi-step reaction with 7 steps

1.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C

1.2: 6 h / 0 °C

2.1: tetrahydrofuran / -78 - 0 °C / Inert atmosphere

3.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 12 h / 25 °C

4.1: tetrahydrofuran / 0 - 25 °C / Inert atmosphere; Molecular sieve

5.1: pyridinium chlorochromate / dichloromethane / 4 h / 25 °C / Inert atmosphere; Molecular sieve

6.1: 2,6-di-tert-butyl-pyridine / nitromethane / 2 h / -20 °C / Inert atmosphere; Molecular sieve

7.1: copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Tetrabutylammoniumsalz der Diphenylphosphinsaeure / N,N-dimethyl-formamide / 16 h / 45 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-pyridine; sodium hydride; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; pyridinium chlorochromate; In tetrahydrofuran; nitromethane; dichloromethane; N,N-dimethyl-formamide; 6.1: Friedel Crafts acylation / 7.1: Stille coupling;
DOI:10.1021/ja301326k