2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

Base Information

Chemical Name:2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester
CAS No.:153996-42-0
Molecular Formula:C₂₅H₄₂O₃Si
Molecular Weight:418.692
Hs Code.:

Synonyms:2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

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Chemical Property of 2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

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Technology Process of 2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

There total 5 articles about 2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 171288-99-6
2,4,6-Trimethyl-benzoic acid (Z)-2-hydroxymethyl-pent-2-enyl ester

: 153996-42-0
2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1021/jo00126a046

Reference yield:

: 133181-02-9,18052-21-6
3-hydroxy-2-methylene-pentanoic acid methyl ester

: 153996-42-0
2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / PPh₃, DEAD / tetrahydrofuran / 0.25 h / 0 °C

2: 84 percent / DIBAL-H / CH₂Cl₂; hexane / -78 °C

3: 100 percent / 2,6-lutidine / CH₂Cl₂

With 2,6-dimethylpyridine; diisobutylaluminium hydride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo00126a046

Reference yield:

: 153996-36-2
Methyl (E)-2-<<(2,4,6-trimethylbenzoyl)oxy>methyl>-2-pentenoate

: 153996-42-0
2,4,6-Trimethyl-benzoic acid (E)-2-triisopropylsilanyloxymethyl-pent-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / DIBAL-H / CH₂Cl₂; hexane / -78 °C

2: 100 percent / 2,6-lutidine / CH₂Cl₂

With 2,6-dimethylpyridine; diisobutylaluminium hydride; In hexane; dichloromethane;
DOI:10.1021/jo00126a046