1,1'-Dibenzyl-4,4'-bipyridinium dichloride

Base Information

• Chemical Name: 1,1'-Dibenzyl-4,4'-bipyridinium dichloride
• CAS No.: 1102-19-8
• Molecular Formula: C24H22Cl2N2
• Molecular Weight: 411.374
• Hs Code.: 29333990
• European Community (EC) Number: 214-158-5
• UNII: YTM57QC5KG
• Mol file: 1102-19-8.mol

Synonyms:1102-19-8;1,1'-Dibenzyl-4,4'-bipyridinium dichloride;1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride;Benzyl viologen dichloride;Benzylviologen chloride;N,N'-Dibenzyl-gamma,gamma'-dipyridylium dichloride;4,4'-Bipyridinium, 1,1'-bis(phenylmethyl)-, dichloride;EINECS 214-158-5;NSC 409418;4,4'-BIPYRIDINIUM, 1,1'-DIBENZYL-, DICHLORIDE;1-benzyl-4-(1-benzylpyridin-1-ium-4-yl)pyridin-1-ium dichloride;1-benzyl-4-(1-benzylpyridin-1-ium-4-yl)pyridin-1-ium;dichloride;1,1'-Bis(phenylmethyl)-4,4'-bipyridinium dichloride;NSC-409418;1,1-DIBENZYL-4,4-BIPYRIDINIUM DICHLORIDE;C24H22N2.2Cl;Benzylviologen dichloride;Dibenzylviologen dichloride;YTM57QC5KG;C24H22Cl2N2;SCHEMBL1930045;Benzyl viologen dichloride, 97%;C24-H22-N2.2Cl;MFCD00011991;AKOS024370927;AS-64431;LS-44640;n,n'-dibenzyl-4,4'-bipyridinium dichloride;C(c1ccccc1)n2ccc(cc2)c3ccn(cc3)Cc4ccccc4;CS-0156500;D2137;FT-0633329;F18656;A802169;J-002401;1,1'-dibenzyl-4,4'-bipyridine-1,1'-diium chloride;1,1'-Dibenzyl-4,4'-bipyridinium Dichloride, Hydrate;1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diiumchloride;1,1'-dibenzyl-[4,4'-bipyridine]-1,1'-diium dichloride;4,4'-Bipyridinium, 1,1'-bis(phenylmethyl)-, chloride (1:2)

Chemical Property of 1,1'-Dibenzyl-4,4'-bipyridinium dichloride

Chemical Property:

• Melting Point: 260
• PSA: 7.76000
• LogP: -1.96680
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 408.1160041
• Heavy Atom Count: 28
• Complexity: 343

Purity/Quality:

99%, ^*data from raw suppliers

1,1''-Dibenzyl-4,4''-bipyridiniumdichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C[N+]2=CC=C(C=C2)C3=CC=[N+](C=C3)CC4=CC=CC=C4.[Cl-].[Cl-]
• General Description: 1,1'-DIBENZYL-4,4'-BIPYRIDINIUM DICHLORIDE (also known as benzyl viologen dichloride) is a viologen homologue that undergoes rapid one-electron reduction to form stable cation radicals when exposed to a radio-frequency gaseous plasma, both in solid and solvated states. The resulting radicals are susceptible to re-oxidation upon air exposure but can be reversibly reduced again. Additionally, its reduction kinetics and solvation dynamics are pressure-dependent, with increased pressure accelerating radical pair decay in solvents like acetonitrile and propylene carbonate, though high pressures in PC can retard the process due to slowed solvent fluctuations. When incorporated into zeolite Y-modified electrodes, its electrochemical behavior remains largely unchanged, but it can participate in charge trapping reactions when paired with surface-adsorbed metalloporphyrins.

Technology Process of 1,1'-Dibenzyl-4,4'-bipyridinium dichloride

There total 4 articles about 1,1'-Dibenzyl-4,4'-bipyridinium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

4,4'-bipyridine (553-26-4) + benzyl chloride (100-44-7) → N,N'-dibenzylviologen dichloride (1102-19-8)

Guidance literature:

In ethanol; 1.) reflux, 4 h, 2.) RT, 2 d;

DOI:10.1021/j150668a041

Reference yield:

C24H22N2(1+)*Cl*Cl(1-) → N,N'-dibenzylviologen dichloride (1102-19-8)

Guidance literature:

In acetonitrile; at 15 ℃; Further Variations:; Pressures; Solvents; Temperatures; Kinetics;

DOI:10.1246/cl.2004.1542

Reference yield:

N,N'-dibenzylviologen dichloride (1102-19-8) → 1,1'-Dibenzyl-1λ5,1'λ5-[4,4']bi[pyridinyl]; compound with chlorine (1102-19-8)

Guidance literature:

With poly(N-vinyl pyrrolidine) matrix; In water; Mechanism; Irradiation; further polymer matrices;

DOI:10.1246/cl.1980.1145

upstream raw materials:

4,4'-bipyridine

benzyl chloride

Downstream raw materials:

benzyl vilogen cation radical

1,1'-dibenzyl-4,4'-bipyridinium

[1,1'-dibenzyl-4,4'-bipyridinium][Pt(maleonitriledithiolate)2]

[1,1'-dibenzyl-4,4'-bipyridinium][Cu(maleonitriledithiolate)2]

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