Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

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Chemical Name:Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester
CAS No.:99478-06-5
Molecular Formula:C₂₆H₄₂O₅
Molecular Weight:434.616
Hs Code.:

Synonyms:Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

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Chemical Property of Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

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Technology Process of Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

There total 11 articles about Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13304-34-2
8a-Methyl-1,2,3,4,6,7,8,8a-octahydro-naphthalen-1-ol

: 99478-06-5
Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: Prⁱ2NEt / CH₂Cl₂ / 8 h / Heating

2: 1.) BH₃, 2.) NaOH, 30percent H₂O₂ / 1.) THF, 0 deg C, 2 h, 2.) 20 deg C, 1 h

3: PCC / CH₂Cl₂ / 2 h / 20 °C

4: NaH / benzene / 3 h / 60 °C

6: oxalic acid / methanol; H₂O / 1 h / 25 °C

7: Me₄NOAc, HMPA / 16 h / 100 °C

8: CuBr / tetrahydrofuran / 1 h / -40 °C

9: NaBH₄, / methanol / 0.17 h / 0 °C

10: py / 16 h / 25 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; sodium tetrahydroborate; borane; tetramethyl ammonium acetate; dihydrogen peroxide; oxalic acid; sodium hydride; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; copper(I) bromide; In tetrahydrofuran; methanol; dichloromethane; water; benzene;
DOI:10.1016/S0040-4039(00)98597-6

Reference yield:

: 20007-99-2,33878-99-8,100348-93-4,20007-72-1
Wieland-Miescher ketone

: 99478-06-5
Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: 1.) NaBH₄, CeCl₃*6H₂O, 2.) LiAlH₄, AlCl₃ / 1.) MeOH, 0 deg C, 15 min, 2.) Et₂O, 0 deg C, 5 h

2: Prⁱ2NEt / CH₂Cl₂ / 8 h / Heating

3: 1.) BH₃, 2.) NaOH, 30percent H₂O₂ / 1.) THF, 0 deg C, 2 h, 2.) 20 deg C, 1 h

4: PCC / CH₂Cl₂ / 2 h / 20 °C

5: NaH / benzene / 3 h / 60 °C

7: oxalic acid / methanol; H₂O / 1 h / 25 °C

8: Me₄NOAc, HMPA / 16 h / 100 °C

9: CuBr / tetrahydrofuran / 1 h / -40 °C

10: NaBH₄, / methanol / 0.17 h / 0 °C

11: py / 16 h / 25 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; aluminium trichloride; cerium(III) chloride; borane; tetramethyl ammonium acetate; dihydrogen peroxide; oxalic acid; sodium hydride; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; copper(I) bromide; In tetrahydrofuran; methanol; dichloromethane; water; benzene;
DOI:10.1016/S0040-4039(00)98597-6

Reference yield:

: (4aS,8aR)-5-Methoxymethoxy-4a-methyl-decahydro-naphthalen-1-ol

: 99478-06-5
Acetic acid (1R,3R,4R)-3-but-3-enyl-4-((2S,4aR,8aS)-5-methoxymethoxy-4a-methyl-1-oxo-decahydro-naphthalen-2-yl)-4-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: PCC / CH₂Cl₂ / 2 h / 20 °C

2: NaH / benzene / 3 h / 60 °C

4: oxalic acid / methanol; H₂O / 1 h / 25 °C

5: Me₄NOAc, HMPA / 16 h / 100 °C

6: CuBr / tetrahydrofuran / 1 h / -40 °C

7: NaBH₄, / methanol / 0.17 h / 0 °C

8: py / 16 h / 25 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; tetramethyl ammonium acetate; oxalic acid; sodium hydride; pyridinium chlorochromate; copper(I) bromide; In tetrahydrofuran; methanol; dichloromethane; water; benzene;
DOI:10.1016/S0040-4039(00)98597-6