9,10-Dihydroanthracene

Base Information

• Chemical Name: 9,10-Dihydroanthracene
• CAS No.: 613-31-0
• Molecular Formula: C14H12
• Molecular Weight: 180.249
• Hs Code.: 2902909090
• European Community (EC) Number: 210-336-1
• NSC Number: 30805
• UNII: Z142C238GB
• DSSTox Substance ID: DTXSID3075256
• Nikkaji Number: J43.471J
• Wikipedia: 9,10-Dihydroanthracene
• Wikidata: Q15634096
• ChEMBL ID: CHEMBL125337
• Mol file: 613-31-0.mol

Synonyms:9,10-DIHYDROANTHRACENE;613-31-0;Anthracene, 9,10-dihydro-;9,10-Dihydro-anthracene;Anthracene, dihydro-;CHEMBL125337;Z142C238GB;EINECS 210-336-1;NSC 30805;NSC-30805;14314-91-1;AI3-09026;NSC30805;MFCD00001239;Anthracene,10-dihydro-;UNII-Z142C238GB;9,10-Dihydroanthracene, 97%;DTXSID3075256;BDBM50060852;STK365298;AKOS004907975;CS-0155867;D0549;FT-0621599;D89677;Q15634096

Chemical Property of 9,10-Dihydroanthracene

Chemical Property:

• Appearance/Colour: brown crystals
• Vapor Pressure: 0.00152mmHg at 25°C
• Melting Point: 103-107 °C(lit.)
• Refractive Index: 1.62
• Boiling Point: 305 °C at 760 mmHg
• Flash Point: 131.8 °C
• PSA: 0.00000
• Density: 1.085 g/cm³
• LogP: 3.18160
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: 1.332mg/L(24.59 oC)
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 180.093900383
• Heavy Atom Count: 14
• Complexity: 154

Purity/Quality:

98% ^*data from raw suppliers

9,10-Dihydroanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 22-24/25-36/37-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1C2=CC=CC=C2CC3=CC=CC=C31
• Uses: 9,10-Dihydroanthracene(DHA) has been used in a study to assess the hydrogen abstraction capability of valence-delocalized iron complex with DHA in MeCN.

Technology Process of 9,10-Dihydroanthracene

There total 188 articles about 9,10-Dihydroanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; water; lithium cation; In N,N-dimethyl-formamide; cathodic reduction;

Reference yield: 99.0%

9,10-phenanthrenequinone (84-65-1) → 9,10-dihydroanthracene (613-31-0)

Guidance literature:

With hydrogen iodide; acetic acid; for 120h; Heating;

DOI:10.1039/b700956a

Reference yield: 98.0%

9-Bromoanthracene (1564-64-3) → 9,10-dihydroanthracene (613-31-0)

Guidance literature:

With manganese(II) chloride dihydrate; lithium; In tetrahydrofuran; at 25 ℃; for 0.5h; Inert atmosphere;

DOI:10.1016/j.tet.2010.04.026

upstream raw materials:

2-Benzoylbenzoic acid

anthracene

anthracen-9(10H)-one

2-benzoylanthracene

Downstream raw materials:

2-(9,10-dioxo-9,10-dihydro-anthracene-2-carbonyl)-benzoic acid

9-benzoyl-9,10-dihydroanthracene

benzo[e]pyrene

anthracene

Refernces

• 1、 Darchen, Andre. "Electron Transfer Catalysis of Arene Deco-ordination in the Cationic (η5-Cyclopentadienyl)(η6-arene)iron(II) Complexes". . p. 768 - 769. Retrieved 1983.
• 2、 Jiang, Jianping,Lai, Yee-Hing. "A novel Birch reduction of aromatic compounds using aqueous titanium trichloride: Anions of trans-10b,10c-dimethyl-2,7,10b,10c-tetrahydropyrene". . p. 1271 - 1274. Retrieved 2003.
• 3、 Bank et al.. "". . p. 4058. Retrieved 1977.
• 4、 Segawa, Yasutomo,Stephan, Douglas W.. "Metal-free hydrogenation catalysis of polycyclic aromatic hydrocarbons". . p. 11963 - 11965. Retrieved 2012.
• 5、 Renaud,R.N.,Stephens,J.C.. "-". . p. 1229 - 1230. Retrieved 1974.
• 6、 Ringel et al.. "". . p. 1956,1959. Retrieved 1970.
• 7、 Philippov,Chibiryaev,Martyanov. "Catalyzed transfer hydrogenation by 2-propanol for highly selective PAHs reduction". . p. 15 - 22. Retrieved 2020/07/15.
• 8、 Huang, Binbin,Guo, Lin,Xia, Wujiong. "A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions". supporting information. p. 2095 - 2103. Retrieved 2021/03/26.