5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

Base Information

Chemical Name:5,5'-( p-BMes₂-phenyl)2-2,2'-bpy
CAS No.:1227401-66-2
Molecular Formula:C₅₈H₅₈B₂N₂
Molecular Weight:804.734
Hs Code.:

5,5'-( p-BMes<sub>2</sub>-phenyl)2-2,2'-bpy

Synonyms:5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

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Chemical Property of 5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

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Technology Process of 5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

There total 1 articles about 5,5'-( p-BMes₂-phenyl)2-2,2'-bpy which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 15862-18-7
5,5'-dibromo-2,2'-dipyridyl

: 38186-40-2
p-bromophenyldimesitylborane

: 1227401-66-2
5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

Guidance literature:: p-bromophenyldimesitylborane; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

With zinc(II) chloride; In tetrahydrofuran; at -78 - 20 ℃;

5,5'-dibromo-2,2'-dipyridyl; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 55 ℃; for 48h;
DOI:10.1021/ic1004159

Reference yield: 82.0%

: 1227401-66-2
5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

: 1227401-71-9
Pt(C₆H₅)2(C₁₀H₆N₂(C₆H₄B(C₆H₂(CH₃)3)2)2)

Guidance literature:: With (Pt(C6H5)2(μ-SMe2)](n) n=2 or 3; In dichloromethane; (N2, Schlenk) a soln. of Pt-complex and bipyridine-compound in CH2Cl2 was stirred for 12 h under N2 at room temp.; the solvent was removed, the residue was washed with diethyl ether and dried under vac.; elem. anal.;
DOI:10.1021/ic1004159

Reference yield: 48.0%

: ammonium hexafluorophosphate

: 1227401-66-2
5,5'-( p-BMes₂-phenyl)2-2,2'-bpy

: 115528-30-8,479081-39-5,864679-58-3
cis-dichlorobis(4,4'-bis(t-butyl)-2,2'-bipyridyl)ruthenium(II)

: Ru(4,4'-bis(t-butyl)-2,2'-bipyridine)2(5,5'-bis(BMes₂phenyl)-2,2'-bipyridine)(PF₆)2

Guidance literature:: In ethanol; (under N2, Schlenk); soln. of Ru-complex and ligand in EtOH refluxed for48 h, cooled to room temp.; concd. under reduced pressure, treated with aq. soln. of NH4PF6, silica gel column chromy. with MeOH:CH2Cl2 1:20; elem. anal.;
DOI:10.1021/ic1021966