(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

Base Information

Chemical Name:(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one
CAS No.:1612868-99-1
Molecular Formula:C₂₄H₃₄O₃
Molecular Weight:370.532
Hs Code.:

Synonyms:(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

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Chemical Property of (4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

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Technology Process of (4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

There total 11 articles about (4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₃₉NO₅Se

: 1612868-99-1
(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

Guidance literature:: With ammonium molybdate; dihydrogen peroxide; In tetrahydrofuran; water; at -10 ℃; for 0.333333h;
DOI:10.1021/ol501304j

Reference yield:

: 1612868-73-1
2,6,6-trimethylnon-2-en-7-yn-5-one

: 1612868-99-1
(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

Guidance literature:: Multi-step reaction with 7 steps

1.1: zinc(II) iodide / dichloromethane / 2 h / Reflux

2.1: diisobutylaluminium hydride / hexane / 0.5 h / -78 - 0 °C

3.1: tert.-butyl lithium / tetrahydrofuran; pentane / -78 - 20 °C

3.2: 5 h / -78 °C

3.3: 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 20 °C

5.1: Amberlyst H-15 / methanol / 48 h / 20 °C

6.1: tributylphosphine / tetrahydrofuran / 0.33 h / 20 °C

7.1: ammonium molybdate; dihydrogen peroxide / tetrahydrofuran; water / 0.33 h / -10 °C

With ammonium molybdate; tributylphosphine; dihydrogen peroxide; tert.-butyl lithium; sodium hydride; diisobutylaluminium hydride; zinc(II) iodide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; mineral oil; pentane; 3.1: |Shapiro Olefination / 3.3: |Shapiro Olefination;
DOI:10.1021/ol501304j

Reference yield:

: 1612868-75-3
5-methyl-2-(2-methylpent-3-yn-2-yl)-2-(trimethylsilyloxy)hex-4-enal

: 1612868-99-1
(4S,5S)-5-((S)-6-allyl-6-methylcyclohex-1-enyl)-4-(3-methylbut-2-enyl)-4-(2-methylpent-3-yn-2-yl)-1,3-dioxolan-2-one

Guidance literature:: Multi-step reaction with 5 steps

1.1: tert.-butyl lithium / tetrahydrofuran; pentane / -78 - 20 °C

1.2: 5 h / -78 °C

1.3: 20 °C

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 20 °C

3.1: Amberlyst H-15 / methanol / 48 h / 20 °C

4.1: tributylphosphine / tetrahydrofuran / 0.33 h / 20 °C

5.1: ammonium molybdate; dihydrogen peroxide / tetrahydrofuran; water / 0.33 h / -10 °C

With ammonium molybdate; tributylphosphine; dihydrogen peroxide; tert.-butyl lithium; sodium hydride; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; mineral oil; pentane; 1.1: |Shapiro Olefination / 1.3: |Shapiro Olefination;
DOI:10.1021/ol501304j