(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

Base Information

Chemical Name:(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester
CAS No.:86661-24-7
Molecular Formula:C₁₈H₂₁ClO₅
Molecular Weight:352.815
Hs Code.:

Synonyms:(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

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Chemical Property of (-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

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Technology Process of (-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

There total 10 articles about (-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 52927-44-3
dimethyl 2-(4-chlorobenzylidene)malonate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 86661-24-7
(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

Guidance literature:: cyclohexanone; With silver hexafluoroantimonate; (2S)-2-amino-3,3-dimethyl-N-(pyridin-2-yl)butanamide; zinc(II) chloride; In tetrahydrofuran; at 20 ℃; for 3h;

dimethyl 2-(4-chlorobenzylidene)malonate; In tetrahydrofuran; at 20 ℃; for 168h; enantioselective reaction;
DOI:10.1021/jo301070s

Reference yield:

: 52927-44-3
dimethyl 2-(4-chlorobenzylidene)malonate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 86661-24-7
2-[(2-oxocyclohexyl)-4-chlorophenylmethyl]malonic acid dimethyl ester

: 86661-24-7
(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

Guidance literature:: cyclohexanone; With C₂₅H₂₂N₂O₄S₂; In water; at 20 ℃; for 0.25h;

dimethyl 2-(4-chlorobenzylidene)malonate; In water; at 20 ℃; for 192h; Overall yield = 64 %; Overall yield = 45 mg; stereoselective reaction;
DOI:10.1002/cjoc.201200910

Reference yield:

: 52927-44-3
dimethyl 2-(4-chlorobenzylidene)malonate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 86661-24-7
2-[(2-oxocyclohexyl)-4-chlorophenylmethyl]malonic acid dimethyl ester

: 86661-24-7
(-)-(1'S,1''S)-<(4-Chlorphenyl)(2-oxocyclohexyl)methyl>propandisaeure-dimethylester

Guidance literature:: cyclohexanone; With C₂₅H₂₂N₂O₄S₂; In water; at 20 ℃; for 0.25h;

dimethyl 2-(4-chlorobenzylidene)malonate; In water; at 20 ℃; for 192h; Overall yield = 64 %; Overall yield = 45 mg; stereoselective reaction;
DOI:10.1002/cjoc.201200910