4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

Base Information

Chemical Name:4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone
CAS No.:330555-93-6
Molecular Formula:C₂₂H₃₃F₃O₄SSi
Molecular Weight:478.648
Hs Code.:

Synonyms:4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

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Chemical Property of 4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

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Technology Process of 4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

There total 5 articles about 4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 330555-92-5
4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5,6-tetrafluorophenyl methyl sulfone

: 330555-93-6
4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

: 4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-3,5-difluoro-2,6-bis(2-trimethylsilylethoxy)phenyl methyl sulfone

Guidance literature:: 2-(Trimethylsilyl)ethanol; With potassium tert-butylate; In tetrahydrofuran; for 0.5h;

4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5,6-tetrafluorophenyl methyl sulfone; In tetrahydrofuran; at 20 ℃; for 1.5h;
DOI:10.1039/b007101n

Reference yield:

: 106-24-1
Geraniol

: 330555-93-6
4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

Guidance literature:: Multi-step reaction with 2 steps

1.1: 75 percent / aq. NaOH; Bu₄N(+)HSO₄(-) / CH₂Cl₂ / 1 h / 20 °C

2.1: t-BuOK / tetrahydrofuran / 0.5 h

2.2: 69 percent / tetrahydrofuran / 1.5 h / 20 °C

With sodium hydroxide; potassium tert-butylate; tetra(n-butyl)ammonium hydrogensulfate; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b007101n

Reference yield:

: 771-62-0
pentafluorophenylthiol

: 330555-93-6
4-[(E)-3,7-Dimethylocta-2,6-dien-1-yloxy]-2,3,5-trifluoro-6-(2-trimethylsilylethoxy)phenyl methyl sulfone

Guidance literature:: Multi-step reaction with 4 steps

1.1: Bu₄N⁽¹⁺⁾*HSO₄^(1-); aq. NaOH / CH₂Cl₂ / 1.08 h

2.1: aq. H₂O₂ / acetic acid / 2 h / 100 °C

3.1: 75 percent / aq. NaOH; Bu₄N(+)HSO₄(-) / CH₂Cl₂ / 1 h / 20 °C

4.1: t-BuOK / tetrahydrofuran / 0.5 h

4.2: 69 percent / tetrahydrofuran / 1.5 h / 20 °C

With sodium hydroxide; potassium tert-butylate; dihydrogen peroxide; tetra(n-butyl)ammonium hydrogensulfate; In tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1039/b007101n