(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

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Chemical Name:(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole
CAS No.:944727-56-4
Molecular Formula:C₃₅H₄₂INO₆
Molecular Weight:699.626
Hs Code.:

Synonyms:(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

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Chemical Property of (2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

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Technology Process of (2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

There total 4 articles about (2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.6%

: 944727-55-3
1-[2-(tert-butyloxycarbonylamino)-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl]-2-propene

: 944727-56-4
(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

Guidance literature:: With iodine; In diethyl ether; dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/jo0700833

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 944727-56-4
(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / triethylamine / methanol / 16 h / 20 °C

2: 89.6 percent / iodine / CH₂Cl₂; diethyl ether / 1 h / 0 °C

With iodine; triethylamine; In methanol; diethyl ether; dichloromethane;
DOI:10.1021/jo0700833

Reference yield:

: 184155-63-3
1-(2'-amino-3',4',6'-tri-O-benzyl-2'-deoxy-α-D-glucopyranosyl)-2-propene

: 944727-56-4
(2S,3aR,5R,6R,7S,7aS)-1-(tert-butyloxycarbonyl)-6,7-di-O-benzyl-2-(iodomethyl)-5-[(benzyloxy)methyl]octahydropyrano[3,2-b]pyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / triethylamine / methanol / 16 h / 20 °C

2: 89.6 percent / iodine / CH₂Cl₂; diethyl ether / 1 h / 0 °C

With iodine; triethylamine; In methanol; diethyl ether; dichloromethane;
DOI:10.1021/jo0700833