(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Base Information

Chemical Name:(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate
CAS No.:110418-32-1
Molecular Formula:C₂₁H₃₃NO₅
Molecular Weight:379.497
Hs Code.:

Synonyms:(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

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Chemical Property of (1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

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Technology Process of (1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

There total 3 articles about (1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 110455-86-2
(1Z,3S,4S,5S)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate

: 110418-32-1
(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In dichloromethane; for 16h; 0 degC to 20 degC;

Reference yield:

: 81445-44-5
(S)-2-(benzyloxy)propanal

: 110418-32-1
(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1: 37.5 percent / diethyl ether / 16 h / -78 °C

2: 97 percent / tBuOOH / 2mol-percent VO(acac)2 / CH₂Cl₂ / 16 h / 0 degC to 20 degC

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In diethyl ether; dichloromethane;

Reference yield:

: 54783-72-1
ethyl (S)-2-(benzyloxy)propionate

: 110418-32-1
(1S,2R,3S,4S,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: Multi-step reaction with 3 steps

1: DIBAH / diethyl ether

3: VO(acac)2, t-BuOOH / CH₂Cl₂; 1,2-dichloro-ethane / 15 h / 25 °C

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; diisobutylaluminium hydride; In diethyl ether; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1055/s-1989-27159