Technology Process of C44H58O13Si
There total 6 articles about C44H58O13Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride;
In
benzene;
for 3h;
Reflux;
DOI:10.1002/chem.201003399
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: palladium 10% on activated carbon; hydrogen; acetic acid / ethyl acetate / 24 h / 20 °C / 750.08 Torr
2.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 1.5 h / -78 - -10 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 2.5 h / -13 - 0 °C
3.2: -78 °C
3.3: -78 - -10 °C
4.1: dmap / dichloromethane / 16.5 h / 0 - 20 °C
5.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / benzene / 3 h / Reflux
With
dmap; n-butyllithium; oxalyl dichloride; 2,2'-azobis(isobutyronitrile); palladium 10% on activated carbon; hydrogen; tri-n-butyl-tin hydride; acetic acid; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane; ethyl acetate; benzene;
2.1: Swern oxidation;
DOI:10.1002/chem.201003399
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 2.5 h / -13 - 0 °C
1.2: -78 °C
1.3: -78 - -10 °C
2.1: dmap / dichloromethane / 16.5 h / 0 - 20 °C
3.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / benzene / 3 h / Reflux
With
dmap; n-butyllithium; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride;
In
tetrahydrofuran; hexane; dichloromethane; benzene;
DOI:10.1002/chem.201003399
