3-hydroxy acetal silyl ether

Base Information

Chemical Name:3-hydroxy acetal silyl ether
CAS No.:105803-40-5
Molecular Formula:C₂₅H₄₂O₄Si
Molecular Weight:434.692
Hs Code.:

Synonyms:3-hydroxy acetal silyl ether

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Chemical Property of 3-hydroxy acetal silyl ether

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of 3-hydroxy acetal silyl ether

There total 20 articles about 3-hydroxy acetal silyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.6%

: 105881-33-2
C₃₈H₅₃NO₅Si

: 105803-40-5
3-hydroxy acetal silyl ether

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 1h; Heating;
DOI:10.1021/jo00389a038

Reference yield:

: 51592-71-3
8,8-dichlorobicyclo<4.2.0>oct-2-en-7-one

: 105803-40-5
3-hydroxy acetal silyl ether

Guidance literature:: Multi-step reaction with 5 steps

1: via bakers yeast reduction

2: 46 percent / Zn / acetic acid / 5 h / 80 °C

3: β-naphthalenesulfonic acid / benzene / 2 h / 90 °C

4: 1.) N-bromoacetamide, 2.) aq. K₂CO₃ / 1.) acetone, 20 deg C, 16 h, 2.) 48 h

5: 1.) n-BuLi, 2.) BF₃*Et₂O / 1.) THF, hexane, 0 deg C, 15 min, 2.) -78 deg C, 90 min

With n-butyllithium; naphthalene-2-sulfonate; boron trifluoride diethyl etherate; potassium carbonate; zinc; N-bromoacetamide; In acetic acid; benzene;
DOI:10.1021/jo00256a011

Reference yield:

: 97563-45-6,105880-38-4,128241-52-1,4187-88-6
1-cyclohexylprop-2-yn-1-ol

: 105803-40-5
3-hydroxy acetal silyl ether

Guidance literature:: Multi-step reaction with 6 steps

1: 82 percent / chromium trioxide, conc. sulfuric acid / acetone / 1 h / 0 °C

2: 1.) (S)-Alpine Borane, 2.) sodium hydroxide, 30 percent hydrogen peroxide / 1.) THF, 23 deg C, 16 h, 2.) THF, 40 deg C, 3 h

3: 71 percent / triethylamine / CH₂Cl₂ / 15 h / Ambient temperature

4: 1.) n-butyllithium, 2.) boron trifluoride etherate / 1.) THF, hexane, 2.) THF, hexane, -78 deg C

5: 40.1 percent / 4-(dimethylamino)pyridine, diisopropylethylamine / 8 h / 45 °C

6: 55.6 percent / LiAlH₄ / tetrahydrofuran / 1 h / Heating

With chromium(VI) oxide; dmap; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; (S)-alpine borane; sulfuric acid; boron trifluoride diethyl etherate; dihydrogen peroxide; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/jo00389a038